Abstract
The aim of this investigation was to study model complexes containing strong p-
ligands as potential nitrogen, oxygen and ligand transfer catalysts. Nitrido containing
cyano complexes of group 6 to 8 metals were selected as potential nitrogen transfer
catalysts. Solid state and solution studies, investigating different aspects of these
systems, were performed. Finally, the knowledge on mechanistic studies were
applied to selected examples of 1st generation Grubbs catalyst [Ru(=CR)(PX3)2Cl2]
(=CR = carbene) to investigate olefin coordination and oxygen decomposition
reactions (both involving strong p-interactions at the metal center thereof).
Prof. A. Roodt