A crystal-chemical investigation of phases of relevance to lime-chromite roast reactions
- Authors: Adendorff, Keith Trevor
- Date: 2014-06-02
- Subjects: Crystallography , Chromite , Mineralogical chemistry , Geochemistry
- Identifier: uj:11309 , http://hdl.handle.net/10210/10901
- Description: M.Sc. (Geology) , Please refer to full text to view abstract
- Full Text:
- Authors: Adendorff, Keith Trevor
- Date: 2014-06-02
- Subjects: Crystallography , Chromite , Mineralogical chemistry , Geochemistry
- Identifier: uj:11309 , http://hdl.handle.net/10210/10901
- Description: M.Sc. (Geology) , Please refer to full text to view abstract
- Full Text:
Carbonate rocks of the Paleoproterozoic Pretoria and Postmasburg Groups, Transvaal Supergroup
- Authors: Swart, Quentin Dax
- Date: 2012-09-05
- Subjects: Carbonate rocks - South Africa , Limestone - South Africa , Dolomite - South Africa , Geochemistry , Mineralogy , Carbon - Isotopes
- Type: Thesis
- Identifier: uj:3562 , http://hdl.handle.net/10210/6946
- Description: M.Sc. , Certain carbonate bearing formations in the Paleoproterozoic Pretoria Group and its Griqualand West equivalent exhibit remarkable geochemical and stable isotopic signatures. The 8'3Ccarb isotopic signatures from the Duitschland and Silverton Formations exhibit large positive excursions, which seemingly coincide with a significant increase in atmospheric oxygen between 2.4 and 2.0 Ga. The Duitschland Formation with its distinctive basal unconformity is composed primarily of limestone and dolomite units, interbedded with two compositionally different shale units and quartzite. Toward the base of the formation there is a distinct conglomeratic quartzite which forms a sequence boundary above which isotopic and geochemical signatures change dramatically. Normal marine isotopic signatures characterize the lower portion of the succession while above the sequence boundari, the carbonates are enriched in "C. This enrichment, however, appears to be the result of local processes occurring within a closed basin. Furthermore it is apparent that the Duitschland Formation (with its three distinct marker beds) is the equivalent of the Rooihoogte Formation and therefore constitutes the base of the Pretoria Group. The Mooidraai Dolomite Formation which outcrops only locally in the Northern Cape Province, is characterized by fenestral and microbially laminated dolomite. The geochemical properties are relatively homogeneous with increases in the FeO and MnO concentrations, resulting from post depositional diagenesis. The stable isotope signatures of these dolomites represent normal marine signatures. There is, however, a depletion in the 813C and 8180 signatures in the ankeritic and sideritic lithofacies, which suggests that this succession was deposited from a stratified water column with respect to the total dissolved CO2. The positive 6 13C excursion present in the carbonates of the Lucknow Formation in Griqualand West, traditionally grouped with the Olifantshoek Group can be correlated with carbonates near the top of the Silverton Formation in the Transvaal area. The latter also displays distinctly positive 6 43C values. One possibility is that if these successions were deposited in closed anoxic basins and that the isotopic anomalies are the result of local processes such as fermentive diagenesis and methanogenesis. However, the close association of the carbonates with shallow marine orthoquartzites suggests that these were deposited in an open marine system and that the positive 8 !3C values reflect a shift in the composition of the ocean water at the time of deposition of the carbonates at 2.2 Ga. Other carbonates present in the Pretoria Group, namely from the Vermont and Houtenbek Formations, display normal open marine 8' 3C values of close to zero. A systematic stratigraphic compilation of all 6 43C values available from the Transvaal Supergroup indicates that two clear-cut positive 5' 3C excursions are present. These excursions were apparently short-lived and well defined and did not occur over an extended period of time as suggested by earlier studies based on global compilations with large uncertainties in radiometric ages of deposits.
- Full Text:
- Authors: Swart, Quentin Dax
- Date: 2012-09-05
- Subjects: Carbonate rocks - South Africa , Limestone - South Africa , Dolomite - South Africa , Geochemistry , Mineralogy , Carbon - Isotopes
- Type: Thesis
- Identifier: uj:3562 , http://hdl.handle.net/10210/6946
- Description: M.Sc. , Certain carbonate bearing formations in the Paleoproterozoic Pretoria Group and its Griqualand West equivalent exhibit remarkable geochemical and stable isotopic signatures. The 8'3Ccarb isotopic signatures from the Duitschland and Silverton Formations exhibit large positive excursions, which seemingly coincide with a significant increase in atmospheric oxygen between 2.4 and 2.0 Ga. The Duitschland Formation with its distinctive basal unconformity is composed primarily of limestone and dolomite units, interbedded with two compositionally different shale units and quartzite. Toward the base of the formation there is a distinct conglomeratic quartzite which forms a sequence boundary above which isotopic and geochemical signatures change dramatically. Normal marine isotopic signatures characterize the lower portion of the succession while above the sequence boundari, the carbonates are enriched in "C. This enrichment, however, appears to be the result of local processes occurring within a closed basin. Furthermore it is apparent that the Duitschland Formation (with its three distinct marker beds) is the equivalent of the Rooihoogte Formation and therefore constitutes the base of the Pretoria Group. The Mooidraai Dolomite Formation which outcrops only locally in the Northern Cape Province, is characterized by fenestral and microbially laminated dolomite. The geochemical properties are relatively homogeneous with increases in the FeO and MnO concentrations, resulting from post depositional diagenesis. The stable isotope signatures of these dolomites represent normal marine signatures. There is, however, a depletion in the 813C and 8180 signatures in the ankeritic and sideritic lithofacies, which suggests that this succession was deposited from a stratified water column with respect to the total dissolved CO2. The positive 6 13C excursion present in the carbonates of the Lucknow Formation in Griqualand West, traditionally grouped with the Olifantshoek Group can be correlated with carbonates near the top of the Silverton Formation in the Transvaal area. The latter also displays distinctly positive 6 43C values. One possibility is that if these successions were deposited in closed anoxic basins and that the isotopic anomalies are the result of local processes such as fermentive diagenesis and methanogenesis. However, the close association of the carbonates with shallow marine orthoquartzites suggests that these were deposited in an open marine system and that the positive 8 !3C values reflect a shift in the composition of the ocean water at the time of deposition of the carbonates at 2.2 Ga. Other carbonates present in the Pretoria Group, namely from the Vermont and Houtenbek Formations, display normal open marine 8' 3C values of close to zero. A systematic stratigraphic compilation of all 6 43C values available from the Transvaal Supergroup indicates that two clear-cut positive 5' 3C excursions are present. These excursions were apparently short-lived and well defined and did not occur over an extended period of time as suggested by earlier studies based on global compilations with large uncertainties in radiometric ages of deposits.
- Full Text:
Modelling of diamond precipitation from fluids in the lower mantle
- Authors: Crossingham, Alexandra
- Date: 2012-06-07
- Subjects: Thermodynamic calculations , Lithospheric mantle , Fluid composition , Diamond precipitation , Diamonds , Kaapvaal Craton , Lithosphere , Geochemistry , Groundwater flow , Precipitation hardening
- Type: Thesis
- Identifier: uj:8648 , http://hdl.handle.net/10210/5004
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
- Authors: Crossingham, Alexandra
- Date: 2012-06-07
- Subjects: Thermodynamic calculations , Lithospheric mantle , Fluid composition , Diamond precipitation , Diamonds , Kaapvaal Craton , Lithosphere , Geochemistry , Groundwater flow , Precipitation hardening
- Type: Thesis
- Identifier: uj:8648 , http://hdl.handle.net/10210/5004
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
Mesoproterozoic volcanism, metallogenesis and tectonic evolution along the western margin of the Kaapvaal Craton
- Authors: Bailie, Russell Hope
- Date: 2010-06-07T06:52:22Z
- Subjects: Geology , Volcanism , Geochemistry , Structural geology , Kaapvaal Craton (South Africa)
- Type: Thesis
- Identifier: uj:6866 , http://hdl.handle.net/10210/3298
- Description: D.Phil. , The western margin of the Archean Kaapvaal Craton, at its contact with the polydeformed and metamorphosed Proterozoic Namaqua Province, is host to four volcanosedimentary successions of Mesoproterozoic age (1.1-1.3 Ga) that occur in close spatial and temporal association to each other. These are the Areachap Group, the Leerkrans Formation of the Wilgenhoutsdrif Group and the two volcanosedimentary successions that comprise the Koras Group. There has been protracted debate as to the exact nature, origin, age and tectonic evolution of these successions, particularly as they occur immediately adjacent to an important crustal suture. A comprehensive whole rock and isotope geochemical study, complemented by zircon-based geochronology where necessary, was thus carried out to characterize and compare the volcanic rocks associated with these four successions. The results are used to assess the role of the four volcanosedimentary successions during the development of the Mesoproterozoic suture between the Kaapvaal Craton and the Namaqua Province during the ~1.2-1.0 Ga Namaquan Orogeny. The geochemical study of the Areachap Group examined a suite of lithologies from different locations along the ~280km long outcrop belt, with the aim of testing the lateral continuity and integrity of this highly metamorphosed and deformed succession. As the bulk of the samples collected were from diamond drill core intersecting volcanogenic massive sulphide (VMS) Zn-Cu deposits it was only appropriate to extend the investigation to assess the metallogenesis and relation of these deposits to their host rock sequences. This included a survey of the sulphur isotope composition of sulphides and sulphates that comprise the Zn-Cu deposits. Furthermore, the architecture and origin of the world-class Copperton deposit, the largest Zn-Cu deposit of the Areachap Group, was examined. For this purpose, available literature data were collated and complemented by new geochemical and geochronological information. Sm-Nd isotopic systematics and U-Pb zircon ages suggest a coeval origin and close genetic link between the metavolcanic rocks of the Leerkrans Formation of the Wilgenhoutsdrif Group and the Areachap Group. Both successions record the establishment of an eastward-directed subduction zone on the western margin of the Kaapvaal Craton. The Areachap Group represents the highly metamorphosed and deformed remnants of a Mesoproterozoic (ca. 1.30-1.24 Ga) volcanic arc that was accreted onto the western margin of the Kaapvaal Craton at ~1.22-1.20 Ga, during the early stages of the Namaquan Orogeny. The igneous protoliths within the Areachap Group are low- to medium-K tholeiitic to calc-alkaline in composition ranging in composition from basaltic through to rhyolitic. Tholeiitic basalts, represented by volumetrically minor amphibolites within the succession have Sm-Nd isotopic characteristics indicative of derivation from a depleted mantle source as denoted by their positive Nd(t) values. The lithogeochemical results highlight the fact that, despite differences in lithological architecture on a local scale, the Areachap Group exhibits coherent geochemical characteristics along its entire strike length.
- Full Text:
- Authors: Bailie, Russell Hope
- Date: 2010-06-07T06:52:22Z
- Subjects: Geology , Volcanism , Geochemistry , Structural geology , Kaapvaal Craton (South Africa)
- Type: Thesis
- Identifier: uj:6866 , http://hdl.handle.net/10210/3298
- Description: D.Phil. , The western margin of the Archean Kaapvaal Craton, at its contact with the polydeformed and metamorphosed Proterozoic Namaqua Province, is host to four volcanosedimentary successions of Mesoproterozoic age (1.1-1.3 Ga) that occur in close spatial and temporal association to each other. These are the Areachap Group, the Leerkrans Formation of the Wilgenhoutsdrif Group and the two volcanosedimentary successions that comprise the Koras Group. There has been protracted debate as to the exact nature, origin, age and tectonic evolution of these successions, particularly as they occur immediately adjacent to an important crustal suture. A comprehensive whole rock and isotope geochemical study, complemented by zircon-based geochronology where necessary, was thus carried out to characterize and compare the volcanic rocks associated with these four successions. The results are used to assess the role of the four volcanosedimentary successions during the development of the Mesoproterozoic suture between the Kaapvaal Craton and the Namaqua Province during the ~1.2-1.0 Ga Namaquan Orogeny. The geochemical study of the Areachap Group examined a suite of lithologies from different locations along the ~280km long outcrop belt, with the aim of testing the lateral continuity and integrity of this highly metamorphosed and deformed succession. As the bulk of the samples collected were from diamond drill core intersecting volcanogenic massive sulphide (VMS) Zn-Cu deposits it was only appropriate to extend the investigation to assess the metallogenesis and relation of these deposits to their host rock sequences. This included a survey of the sulphur isotope composition of sulphides and sulphates that comprise the Zn-Cu deposits. Furthermore, the architecture and origin of the world-class Copperton deposit, the largest Zn-Cu deposit of the Areachap Group, was examined. For this purpose, available literature data were collated and complemented by new geochemical and geochronological information. Sm-Nd isotopic systematics and U-Pb zircon ages suggest a coeval origin and close genetic link between the metavolcanic rocks of the Leerkrans Formation of the Wilgenhoutsdrif Group and the Areachap Group. Both successions record the establishment of an eastward-directed subduction zone on the western margin of the Kaapvaal Craton. The Areachap Group represents the highly metamorphosed and deformed remnants of a Mesoproterozoic (ca. 1.30-1.24 Ga) volcanic arc that was accreted onto the western margin of the Kaapvaal Craton at ~1.22-1.20 Ga, during the early stages of the Namaquan Orogeny. The igneous protoliths within the Areachap Group are low- to medium-K tholeiitic to calc-alkaline in composition ranging in composition from basaltic through to rhyolitic. Tholeiitic basalts, represented by volumetrically minor amphibolites within the succession have Sm-Nd isotopic characteristics indicative of derivation from a depleted mantle source as denoted by their positive Nd(t) values. The lithogeochemical results highlight the fact that, despite differences in lithological architecture on a local scale, the Areachap Group exhibits coherent geochemical characteristics along its entire strike length.
- Full Text:
Diagenetic carbonates and biogeochemical cycling of organic matter in selected Archean-Paleoproterozoic sedimentary successions of the Kaapvaal Craton, South Africa
- Authors: Cochrane, Justin Michael
- Date: 2010-06-03T05:38:44Z
- Subjects: Stratigraphic geology , Geochemistry , Petrology , Mineralogy , Sedimentation and deposition , Kaapvaal Craton (South Africa)
- Type: Thesis
- Identifier: uj:6855 , http://hdl.handle.net/10210/3288
- Description: M.Sc. , The Kaapvaal craton is one of few regions on earth with an almost continuous record of wellpreserved supracrustal rocks ranging in age from ~3.5 Ga to the late Paleoproterozoic at ~1.75 Ga. In this study diagenetic carbonates from the Paleoarchean Buck Reef Chert and Joe’s Luck Formation of the Swaziland Supergroup, the Mesoarchean Thalu and Promise Formations of the Mozaan/Witwatersrand Supergroups and the Paleoproterozoic Timeball Hill and Silverton Formations of the Transvaal Supergroup were sampled and analyzed. The aim of the study was to determine possible variations in the composition of the carbonates through time and their significance especially with regards to microbial activity in diagenetic systems in early Earth history. Results indicate similar petrographic observations and geochemical signatures in diagenetic carbonates of iron formations in the Buck Reef Chert, Joe’s Luck and Griquatown Iron Formation. The carbonates all tend to be siderites with iron derived from hydrothermal input and all are depleted in 13C relative to Peedee Belemnite standard. It suggested that siderite formed as a result of microbial respiration. Microbes degrade organic matter and reduce iron in this process. This resulted in the depletion in 13C and in the precipitation of siderite. However in order for iron reduction to have occurred the reduced iron first had to be oxidized. This most probably occurred through iron oxidizing chemolithoautotrophs under microaerophilic conditions. Diagenetic carbonate concretions of the Thalu and Promise Formations are manganiferous and are highly depleted in 13C relative to PDB. There is also strong evidence for hydrothermal input of manganese and iron into the system because of positive europium anomalies. The carbonates from both of the formations strongly suggest the presence of some free oxygen. The reasoning behind this conclusion is as follows: The depletion of 13C in the carbonates points to microbial decomposition of organic matter and manganese respiration (the decomposition of organic matter by microbial MnO2 reduction) is shown to be the most reasonable process that led to the formation of the carbonate concretions. The implication is that MnO2 must first have been precipitated and that can only be achieved in the presence of free oxygen with the oxidation reaction often catalyzed by manganese oxidizing chemolithoautotrophs. The carbonates of the Timeball Hill and Silverton Formationsare calcites ad contain little no iron. There is also little or no evidence for hydrothermal input and the basin appears to be a clastic dominated. It is generally accepted that a major rise in oxygen in the oceans and the atmosphere occurred at about 2.32 Ga. This rise in oxygen levels is reflected in the diagenetic calcite concretions of the Silverton Formation. Both iron and manganese reduction where not very effective because of the depletion in the basin water of these two elements, organic carbon taken up in the calcite concretions, indicated by negative δ13CPDB carbonate values, was most probably derived from aerobic and/or nitrate respiration. The most important conclusion from this study is that sufficient free oxygen and hence oxygenic photosynthesis were present to oxidize both Fe and Mn at least as far back as the Paleo-Mesoarchean.
- Full Text:
- Authors: Cochrane, Justin Michael
- Date: 2010-06-03T05:38:44Z
- Subjects: Stratigraphic geology , Geochemistry , Petrology , Mineralogy , Sedimentation and deposition , Kaapvaal Craton (South Africa)
- Type: Thesis
- Identifier: uj:6855 , http://hdl.handle.net/10210/3288
- Description: M.Sc. , The Kaapvaal craton is one of few regions on earth with an almost continuous record of wellpreserved supracrustal rocks ranging in age from ~3.5 Ga to the late Paleoproterozoic at ~1.75 Ga. In this study diagenetic carbonates from the Paleoarchean Buck Reef Chert and Joe’s Luck Formation of the Swaziland Supergroup, the Mesoarchean Thalu and Promise Formations of the Mozaan/Witwatersrand Supergroups and the Paleoproterozoic Timeball Hill and Silverton Formations of the Transvaal Supergroup were sampled and analyzed. The aim of the study was to determine possible variations in the composition of the carbonates through time and their significance especially with regards to microbial activity in diagenetic systems in early Earth history. Results indicate similar petrographic observations and geochemical signatures in diagenetic carbonates of iron formations in the Buck Reef Chert, Joe’s Luck and Griquatown Iron Formation. The carbonates all tend to be siderites with iron derived from hydrothermal input and all are depleted in 13C relative to Peedee Belemnite standard. It suggested that siderite formed as a result of microbial respiration. Microbes degrade organic matter and reduce iron in this process. This resulted in the depletion in 13C and in the precipitation of siderite. However in order for iron reduction to have occurred the reduced iron first had to be oxidized. This most probably occurred through iron oxidizing chemolithoautotrophs under microaerophilic conditions. Diagenetic carbonate concretions of the Thalu and Promise Formations are manganiferous and are highly depleted in 13C relative to PDB. There is also strong evidence for hydrothermal input of manganese and iron into the system because of positive europium anomalies. The carbonates from both of the formations strongly suggest the presence of some free oxygen. The reasoning behind this conclusion is as follows: The depletion of 13C in the carbonates points to microbial decomposition of organic matter and manganese respiration (the decomposition of organic matter by microbial MnO2 reduction) is shown to be the most reasonable process that led to the formation of the carbonate concretions. The implication is that MnO2 must first have been precipitated and that can only be achieved in the presence of free oxygen with the oxidation reaction often catalyzed by manganese oxidizing chemolithoautotrophs. The carbonates of the Timeball Hill and Silverton Formationsare calcites ad contain little no iron. There is also little or no evidence for hydrothermal input and the basin appears to be a clastic dominated. It is generally accepted that a major rise in oxygen in the oceans and the atmosphere occurred at about 2.32 Ga. This rise in oxygen levels is reflected in the diagenetic calcite concretions of the Silverton Formation. Both iron and manganese reduction where not very effective because of the depletion in the basin water of these two elements, organic carbon taken up in the calcite concretions, indicated by negative δ13CPDB carbonate values, was most probably derived from aerobic and/or nitrate respiration. The most important conclusion from this study is that sufficient free oxygen and hence oxygenic photosynthesis were present to oxidize both Fe and Mn at least as far back as the Paleo-Mesoarchean.
- Full Text:
Textural and geochemical evidence for a supergene origin of the Paleoproterozoic high-grade BIF-hosted iron ores of the Maremane Dome, Northern Cape Province, South Africa
- Van Deventer, Wikus Frederick
- Authors: Van Deventer, Wikus Frederick
- Date: 2010-05-27T06:07:22Z
- Subjects: Geology , Iron ores , Geochemistry , Northern Cape (South Africa)
- Type: Thesis
- Identifier: uj:6850 , http://hdl.handle.net/10210/3281
- Description: M.Sc. , Biofuels have the potential to reduce a country’s dependence on imported oil, to ensure diversity of energy sources, to increase the availability of renewable energy sources and to address global environmental issues. In recognition of the potential benefits of the production and use of biofuels, the Department of Minerals and Energy released the Draft Biofuels Industrial Strategy in December 2006 with the aim to increase the use of biofuels in South Africa to replace 4.5% of conventional transport fuels by 2013. However, there are several barriers that need to be overcome before South Africa can establish a large-scale biofuel industry to achieve the DME’s biofuel target. This includes environmental barriers, such as the availability of land for the cultivation of biofuel feedstocks and potential threats to food security. This study focuses on these environmental barriers and aims to determine the potential for bioethanol production from maize in South Africa to 2013. To this purpose, a bioethanol potential model is developed to simulate the potential for bioethanol production from maize in South Africa between 2008 and 2013. The model incorporates four key elements that all impact on the availability of maize for bioethanol production, namely: maize demand; maize supply; the demand for maize as biomaterial; and the available land area for the cultivation of maize. The study makes further use of the scenario planning method to determine the potential for bioethanol production from maize in South Africa. Four unique bioethanol potential scenarios are designed and simulated within the bioethanol potential model developed for this purpose. Each scenario plays out a different Abstract storyline for the future social, economic and natural environment that will impact on the availability of maize for bioethanol production. The results of the bioethanol potential scenario simulations show that South Africa will be able to produce enough maize to meet the DME’s biofuel target of 1.2 billion liters of bioethanol for all scenarios between 2009 and 2010. From 2011 onwards, the bioethanol potential decreases below the DME’s target value in both the worst case and rapid change scenarios. The study concludes that the production of bioethanol from maize in South Africa will have various social, economic and environmental consequences for the country’s agricultural sector. The depletion of domestic maize supplies will seriously threaten food security and consequently, increase the country’s dependence on maize imports. This will not only affect the country’s maize producing regions, but spread throughout South Africa as the demand for agriculturally productive land for maize production increases. Domestic food security is therefore at risk and South Africa will have to resort to other energy technologies to achieve a sustainable and renewable energy future for road transport.
- Full Text:
- Authors: Van Deventer, Wikus Frederick
- Date: 2010-05-27T06:07:22Z
- Subjects: Geology , Iron ores , Geochemistry , Northern Cape (South Africa)
- Type: Thesis
- Identifier: uj:6850 , http://hdl.handle.net/10210/3281
- Description: M.Sc. , Biofuels have the potential to reduce a country’s dependence on imported oil, to ensure diversity of energy sources, to increase the availability of renewable energy sources and to address global environmental issues. In recognition of the potential benefits of the production and use of biofuels, the Department of Minerals and Energy released the Draft Biofuels Industrial Strategy in December 2006 with the aim to increase the use of biofuels in South Africa to replace 4.5% of conventional transport fuels by 2013. However, there are several barriers that need to be overcome before South Africa can establish a large-scale biofuel industry to achieve the DME’s biofuel target. This includes environmental barriers, such as the availability of land for the cultivation of biofuel feedstocks and potential threats to food security. This study focuses on these environmental barriers and aims to determine the potential for bioethanol production from maize in South Africa to 2013. To this purpose, a bioethanol potential model is developed to simulate the potential for bioethanol production from maize in South Africa between 2008 and 2013. The model incorporates four key elements that all impact on the availability of maize for bioethanol production, namely: maize demand; maize supply; the demand for maize as biomaterial; and the available land area for the cultivation of maize. The study makes further use of the scenario planning method to determine the potential for bioethanol production from maize in South Africa. Four unique bioethanol potential scenarios are designed and simulated within the bioethanol potential model developed for this purpose. Each scenario plays out a different Abstract storyline for the future social, economic and natural environment that will impact on the availability of maize for bioethanol production. The results of the bioethanol potential scenario simulations show that South Africa will be able to produce enough maize to meet the DME’s biofuel target of 1.2 billion liters of bioethanol for all scenarios between 2009 and 2010. From 2011 onwards, the bioethanol potential decreases below the DME’s target value in both the worst case and rapid change scenarios. The study concludes that the production of bioethanol from maize in South Africa will have various social, economic and environmental consequences for the country’s agricultural sector. The depletion of domestic maize supplies will seriously threaten food security and consequently, increase the country’s dependence on maize imports. This will not only affect the country’s maize producing regions, but spread throughout South Africa as the demand for agriculturally productive land for maize production increases. Domestic food security is therefore at risk and South Africa will have to resort to other energy technologies to achieve a sustainable and renewable energy future for road transport.
- Full Text:
The Paleo-environmental significance of the iron-formations and iron-rich mudstones of the Mesoarchean Witwatersrand-Mozaan Basin, South Africa
- Smith, Albertus Johannes Basson
- Authors: Smith, Albertus Johannes Basson
- Date: 2009-04-28T07:17:48Z
- Subjects: Geology , Petrology , Mineralogy , Geochemistry , Iron ores , Formations (Geology)
- Type: Thesis
- Identifier: http://ujcontent.uj.ac.za8080/10210/370928 , uj:8312 , http://hdl.handle.net/10210/2440
- Description: M.Sc. , The Mesoarchean Witwatersrand and Pongola Supergroups of South Africa are the oldest, well preserved supracratonic successions worldwide. Various banded iron formation (BIF) and iron-rich mudstone units occur within the West Rand Group of the Witwatersrand Supergroup and the Mozaan Group of the Pongola Supergroup. A granular iron formation (GIF) occurs in a single unit in the Nconga Formation of the Mozaan Group. The Witwatersrand Supergroup and Mozaan Group have been lithostratigraphically correlated and are interpreted to have been part of the same sedimentary basin. The studied BIF units occur in two associations: shale-associated and diamictiteassociated BIF. The GIF seem to have been deposited in shallower environments with greater hydrodynamic activity. The iron-rich mudstone shows a similar stratigraphic setting to that of the shale-associated BIF. The lithostratigraphic setting of the Witwatersrand-Mozaan basin BIFs are similar to what is seen for Superior-type ironformations, with the mudstones and associated BIFs marking marine transgressions. Various mineralogical facies of BIF were identified, including oxide, carbonate and silicate facies BIF, as well as mixed facies between these end members. The GIF is a unique facies and shows abundant petrographic evidence for biological activity. The iron-rich mudstone has been subdivided into iron-silicate rich, magnetite-bearing, carbonate-bearing, magnetite-carbonate-bearing and garnet-bearing subtypes. BIF, GIF and iron-rich mudstone have been subjected to lower greenschist facies metamorphism with some occurences of localized contact metamorphism. The abundance of magnetite shows that oxidation played an important part in BIF deposition, whereas the occurrence of 12C-enriched iron-rich carbonates suggests post depositional reduction of the deposited oxidized iron-rich minerals by organic matter. Al-bearing minerals are rare in the BIFs xxi and abundant in the iron-rich mudstones. Apatite and rare earth element (REE)- phosphates occur throughout. The major element geochemistry shows an inverse proportionality for Fe and Si in all the studied samples. BIFs show slightly higher Fe- and lower Si- and Al-concentrations compared to iron-rich mudstones which show higher Si- and Al- and lower Feconcentrations. The studied BIFs show major element geochemical attributes intermediate to those of Superior- and Algoma-type iron-formations. Provenance studies on some of the iron-rich mudstones illustrate that they were sourced from a mixture of mafic and felsic sources. The rare earth element (REE) geochemistry suggests strong hydrothermal input into the units, and positive correlation with the Fe-concentrations suggests that the Fe was introduced by high temperature hydrothermal fluids. The majority of the REEs are hosted by apatite and the REE-phosphates monazite and xenotime. The REEs were reconcentrated into these phosphates during diagenesis. A comparison of the studied lithostratigraphically correlatable units between the Witwatersrand Supergroup and Mozaan Group makes it possible to construct a depositional model for basin-wide BIF deposition in the Witwatersrand-Mozaan basin. Shale-associated BIF was deposited during the peak of transgression when reduced Ferich hydrothermal bottom waters were introduced into shallow ocean water that was either oxygenated or filled with anoxygenic phototrophic bacteria. Diamictite-associated BIF, in contrast, was deposited during interglacial periods when the melting of glacial ice introduced sunlight, nutrients and oxygen to the reduced, hydrothermally influenced Ferich ocean water. GIF was probably deposited in shallow, above wave base waters cut off from clastic input, and then washed into deeper depositional environments. Iron-rich mudstone was deposited in a similar setting as the shale-associated BIF, but in environments that were not completely cut off from detrital influx. The study shows that it is impossible to construct a general depositional model for Precambrian BIFs, since the lithostratigraphic and depositional settings vary between different examples of BIF.
- Full Text:
- Authors: Smith, Albertus Johannes Basson
- Date: 2009-04-28T07:17:48Z
- Subjects: Geology , Petrology , Mineralogy , Geochemistry , Iron ores , Formations (Geology)
- Type: Thesis
- Identifier: http://ujcontent.uj.ac.za8080/10210/370928 , uj:8312 , http://hdl.handle.net/10210/2440
- Description: M.Sc. , The Mesoarchean Witwatersrand and Pongola Supergroups of South Africa are the oldest, well preserved supracratonic successions worldwide. Various banded iron formation (BIF) and iron-rich mudstone units occur within the West Rand Group of the Witwatersrand Supergroup and the Mozaan Group of the Pongola Supergroup. A granular iron formation (GIF) occurs in a single unit in the Nconga Formation of the Mozaan Group. The Witwatersrand Supergroup and Mozaan Group have been lithostratigraphically correlated and are interpreted to have been part of the same sedimentary basin. The studied BIF units occur in two associations: shale-associated and diamictiteassociated BIF. The GIF seem to have been deposited in shallower environments with greater hydrodynamic activity. The iron-rich mudstone shows a similar stratigraphic setting to that of the shale-associated BIF. The lithostratigraphic setting of the Witwatersrand-Mozaan basin BIFs are similar to what is seen for Superior-type ironformations, with the mudstones and associated BIFs marking marine transgressions. Various mineralogical facies of BIF were identified, including oxide, carbonate and silicate facies BIF, as well as mixed facies between these end members. The GIF is a unique facies and shows abundant petrographic evidence for biological activity. The iron-rich mudstone has been subdivided into iron-silicate rich, magnetite-bearing, carbonate-bearing, magnetite-carbonate-bearing and garnet-bearing subtypes. BIF, GIF and iron-rich mudstone have been subjected to lower greenschist facies metamorphism with some occurences of localized contact metamorphism. The abundance of magnetite shows that oxidation played an important part in BIF deposition, whereas the occurrence of 12C-enriched iron-rich carbonates suggests post depositional reduction of the deposited oxidized iron-rich minerals by organic matter. Al-bearing minerals are rare in the BIFs xxi and abundant in the iron-rich mudstones. Apatite and rare earth element (REE)- phosphates occur throughout. The major element geochemistry shows an inverse proportionality for Fe and Si in all the studied samples. BIFs show slightly higher Fe- and lower Si- and Al-concentrations compared to iron-rich mudstones which show higher Si- and Al- and lower Feconcentrations. The studied BIFs show major element geochemical attributes intermediate to those of Superior- and Algoma-type iron-formations. Provenance studies on some of the iron-rich mudstones illustrate that they were sourced from a mixture of mafic and felsic sources. The rare earth element (REE) geochemistry suggests strong hydrothermal input into the units, and positive correlation with the Fe-concentrations suggests that the Fe was introduced by high temperature hydrothermal fluids. The majority of the REEs are hosted by apatite and the REE-phosphates monazite and xenotime. The REEs were reconcentrated into these phosphates during diagenesis. A comparison of the studied lithostratigraphically correlatable units between the Witwatersrand Supergroup and Mozaan Group makes it possible to construct a depositional model for basin-wide BIF deposition in the Witwatersrand-Mozaan basin. Shale-associated BIF was deposited during the peak of transgression when reduced Ferich hydrothermal bottom waters were introduced into shallow ocean water that was either oxygenated or filled with anoxygenic phototrophic bacteria. Diamictite-associated BIF, in contrast, was deposited during interglacial periods when the melting of glacial ice introduced sunlight, nutrients and oxygen to the reduced, hydrothermally influenced Ferich ocean water. GIF was probably deposited in shallow, above wave base waters cut off from clastic input, and then washed into deeper depositional environments. Iron-rich mudstone was deposited in a similar setting as the shale-associated BIF, but in environments that were not completely cut off from detrital influx. The study shows that it is impossible to construct a general depositional model for Precambrian BIFs, since the lithostratigraphic and depositional settings vary between different examples of BIF.
- Full Text:
Provenance of the Neoproterozoic to early Palaeozoic successions of the Kango Inlier, Saldania Belt, South Africa
- Authors: Naidoo, Thanusha
- Date: 2009-04-28T06:57:55Z
- Subjects: Geology , Petrology , Geochemistry , Geological time , Cape of Good Hope (South Africa)
- Type: Thesis
- Identifier: uj:8308 , http://hdl.handle.net/10210/2437
- Description: M.Sc. , The configuration of the supercontinent Rodinia, at the end of the Mesoproterozoic to the beginning of the Neoproterozoic (1100-750 Ma), and its subsequent break up into cratonic fragments that would later result in the formation of Gondwana (Early Palaeozoic), is still not completely understood. This is largely due to ambiguity surrounding relationships between cratons, craton evolution and timing of significant tectonic or sedimentary events. Particular to this study is the evolution and palaeogeographic history of the Kalahari Craton and a comprehensive provenance analysis of Neoproterozoic to early Palaeozoic clastic sedimentary rocks from the Kango Inlier (Saldania Belt, South Africa). This includes the Cango Caves and Kansa Groups as well as the Schoemanspoort and the adjacent Peninsula Formation (Table Mountain Group, Cape Supergroup). A well established lithostratigraphy, in addition to recent establishment of age constraints by UPb zircon dating and microfossil evidence, allowed for strategic sampling with the objective of gaining insight to the crustal evolution of SW Gondwana. In this study, a progression from immature, moderately altered rocks in the Cango Caves Group (Upper Neoproterozoic) to mature, strongly altered rocks in the Lower Palaeozoic Kansa Group and overlying formations is observed. Thus, rapid sedimentation of the former is anticipated, while the subsequent formations developed at a passive/rifted margin culminating in the laterally extensive deposition of the Peninsula Formation. Ongoing extensional movement is evident due to chronologically deeper-water facies and the progressive influence of a less fractionated component in the Cango Caves Group, particularly in the Huis Rivier Formation. The association of these rocks with an active margin is not certain since index trace element concentrations are too high for typical arc terranes. Thus, the mixing of a younger (570-600 Ma) magmatic source (close to an active margin) with mafic and felsic rocks of the older Mesoproterozoic Natal- Namaqua Mobile Belt (NMB) is the most likely possibility. A maximum, pre-Cape Granite age of 571 Ma can be assigned to the Huis Rivier Formation (Cango Caves Group) by detrital zircon dating, and thus correlation with the Malmesbury Group can be made. Ediacaran age zircons might be related to the active continental margin (Trans Antarctic Orogen) surrounding southern Gondwana, but this is still hypothetical. The post-Cape Granite Kansa Group and overlying Schoemanspoort Formation were most likely deposited as basin infill subsequent to folding and transtensional tectonics affecting the underlying Cango Caves Group. The Kansa Group may be comparable with the Klipheuwel Formation (southwest South Africa) in terms of its stratigraphic position beneath the Table Mountain Group. Deposition of the Table Mountain Group is much younger than previously believed in light of Ordovician zircon ages (471, 485, 499 Ma) obtained from the underlying Kansa Group. However, the provenance of these thus far unheard of ages for magmatic events in South Africa is a matter of contention. The proximal Ordovician Ross-Delamerian Orogenic event in Antarctica is the most likely source. Peninsula Formation deposition represents a cover sequence i.e. the culmination of small isolated basins (e.g. the Kansa Group and lower Table Mountain Group) into a larger, laterally extensive basin where reworking played a dominant role. This basin is likely to be a rift-related. However, it is not clear which crustal entity rifted away from vi South Africa and if, during the Ordovician an, active continental margin further to the south - bridging the South American Famatina Orogen with the Ross-Delamerian arc in Antarctica - existed. The Natal-Namaqua Mobile Belt appears to be the predominant source throughout the succession as indicated by Nd-isotope data and zircon populations. This implies that simple crustal recycling of Natal-Namaqua basement (or rocks with similar Nd-isotope characteristics) led to the genesis of the magmatic material younger than 1 Ga, observed in this study.
- Full Text:
- Authors: Naidoo, Thanusha
- Date: 2009-04-28T06:57:55Z
- Subjects: Geology , Petrology , Geochemistry , Geological time , Cape of Good Hope (South Africa)
- Type: Thesis
- Identifier: uj:8308 , http://hdl.handle.net/10210/2437
- Description: M.Sc. , The configuration of the supercontinent Rodinia, at the end of the Mesoproterozoic to the beginning of the Neoproterozoic (1100-750 Ma), and its subsequent break up into cratonic fragments that would later result in the formation of Gondwana (Early Palaeozoic), is still not completely understood. This is largely due to ambiguity surrounding relationships between cratons, craton evolution and timing of significant tectonic or sedimentary events. Particular to this study is the evolution and palaeogeographic history of the Kalahari Craton and a comprehensive provenance analysis of Neoproterozoic to early Palaeozoic clastic sedimentary rocks from the Kango Inlier (Saldania Belt, South Africa). This includes the Cango Caves and Kansa Groups as well as the Schoemanspoort and the adjacent Peninsula Formation (Table Mountain Group, Cape Supergroup). A well established lithostratigraphy, in addition to recent establishment of age constraints by UPb zircon dating and microfossil evidence, allowed for strategic sampling with the objective of gaining insight to the crustal evolution of SW Gondwana. In this study, a progression from immature, moderately altered rocks in the Cango Caves Group (Upper Neoproterozoic) to mature, strongly altered rocks in the Lower Palaeozoic Kansa Group and overlying formations is observed. Thus, rapid sedimentation of the former is anticipated, while the subsequent formations developed at a passive/rifted margin culminating in the laterally extensive deposition of the Peninsula Formation. Ongoing extensional movement is evident due to chronologically deeper-water facies and the progressive influence of a less fractionated component in the Cango Caves Group, particularly in the Huis Rivier Formation. The association of these rocks with an active margin is not certain since index trace element concentrations are too high for typical arc terranes. Thus, the mixing of a younger (570-600 Ma) magmatic source (close to an active margin) with mafic and felsic rocks of the older Mesoproterozoic Natal- Namaqua Mobile Belt (NMB) is the most likely possibility. A maximum, pre-Cape Granite age of 571 Ma can be assigned to the Huis Rivier Formation (Cango Caves Group) by detrital zircon dating, and thus correlation with the Malmesbury Group can be made. Ediacaran age zircons might be related to the active continental margin (Trans Antarctic Orogen) surrounding southern Gondwana, but this is still hypothetical. The post-Cape Granite Kansa Group and overlying Schoemanspoort Formation were most likely deposited as basin infill subsequent to folding and transtensional tectonics affecting the underlying Cango Caves Group. The Kansa Group may be comparable with the Klipheuwel Formation (southwest South Africa) in terms of its stratigraphic position beneath the Table Mountain Group. Deposition of the Table Mountain Group is much younger than previously believed in light of Ordovician zircon ages (471, 485, 499 Ma) obtained from the underlying Kansa Group. However, the provenance of these thus far unheard of ages for magmatic events in South Africa is a matter of contention. The proximal Ordovician Ross-Delamerian Orogenic event in Antarctica is the most likely source. Peninsula Formation deposition represents a cover sequence i.e. the culmination of small isolated basins (e.g. the Kansa Group and lower Table Mountain Group) into a larger, laterally extensive basin where reworking played a dominant role. This basin is likely to be a rift-related. However, it is not clear which crustal entity rifted away from vi South Africa and if, during the Ordovician an, active continental margin further to the south - bridging the South American Famatina Orogen with the Ross-Delamerian arc in Antarctica - existed. The Natal-Namaqua Mobile Belt appears to be the predominant source throughout the succession as indicated by Nd-isotope data and zircon populations. This implies that simple crustal recycling of Natal-Namaqua basement (or rocks with similar Nd-isotope characteristics) led to the genesis of the magmatic material younger than 1 Ga, observed in this study.
- Full Text:
Petrology, geochemistry and geochronology of Neoproterozoic volcanic rocks of the Punagarh and Sindreth Groups, Rajasthan, northwest India
- Authors: Van Lente, Belinda
- Date: 2009-01-28T09:44:02Z
- Subjects: Stratigraphy geology , Petrology , Geochemistry , Volcanic ash , Rajasthan (India)
- Type: Thesis
- Identifier: http://ujcontent.uj.ac.za8080/10210/364082 , uj:14851 , http://hdl.handle.net/10210/1973
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
- Authors: Van Lente, Belinda
- Date: 2009-01-28T09:44:02Z
- Subjects: Stratigraphy geology , Petrology , Geochemistry , Volcanic ash , Rajasthan (India)
- Type: Thesis
- Identifier: http://ujcontent.uj.ac.za8080/10210/364082 , uj:14851 , http://hdl.handle.net/10210/1973
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
The Pongola Supergroup in Swaziland
- Authors: Nhleko, Noah
- Date: 2009-01-28T09:42:41Z
- Subjects: Geology , Stratigraphic geology , Geochemistry , Paleomagnetism
- Type: Thesis
- Identifier: uj:14843 , http://hdl.handle.net/10210/1966
- Description: D.Phil. , The Mesoarchean Pongola Supergroup, cropping out in the southeastern region of the Kaapvaal craton, is one of the oldest known supracrustal successions in the world. It represents an erosional remnant of a once extensive cratonic cover sequence. The succession is subdivided into the lower Nsuze Group, a volcano sedimentary succession, and the Mozaan Group composed mainly of siliciclastics and minor volcanics. The Mozaan Group is host to the world’s oldest known glacial deposit. The Pongola Supergroup is well preserved both geochemically and structurally. Outcrops extend from the northern part of KwaZulu-Natal and Mpumalanga Province in South Africa into Swaziland. This study presents results of an integrated stratigraphic, sedimentological, geochemical, geochronological, and paleomagnetic investigation of the Pongola Supergroup in Swaziland and drill cores from the Nongoma Graben in KwaZulu-Natal. The Nsuze Group displays marked cyclicity between volcanic and siliciclastic rocks that were probably deposited in an intracratonic ‘sag and dome’ basin. The volcanicsedimentary cycles are thought to represent periodic heat loss from a hot regional mantle beneath the Kaapvaal craton. In the sag basins the rate of subsidence was gradual and sedimentation marked by near shore deposition. Volcanism in the Agatha Formation was episodic and displays a cyclicity of 2-14Myr in duration. Magmatic eruption was marked by the development of a low crustal level magma chamber. Crustal contamination trough assimilation and fractional crystallization at these low crustal level magma storages is recorded by compositional bimodal volcanism of basaltic andesite-rhyodacite and andesite-rhyolite association. After cessation of the volcanism of the Nsuze Group, subsequent development of the Pongola basin was marked by thermal subsidence and marine transgression in an epicratonic basin, at the time of deposition of the Mozaan Group. The Mozaan Group overlies the Nsuze Group with an erosive unconformity developed over an in situ weathering profile, i.e. a paleosol. The Mozaan Group consists of alternating quartzite, shale, conglomerate, iron-formation. Three units of contemporaneous flood basalt, namely the Tobolsk, Gabela and Ntanyana formations are interbedded with the siliciclastic deposits in the upper part of the succession. Unimodal paleocurrent directions based on fluvial quartzites indicate initial provenances to the south and north. This indicates that the basin morphology was in a form of a trough. Eventually paleocurrent distribution patterns turn southeast, and marine flooding extended further towards the west, to form the Greater Witwatersrand Basin, which was then modified by development of a foreland basin towards the west and northwest. This suggests that the present outcrops of the Mozaan Group represent mere remnants of an extensive basin. Siliciclastic deposits of the Mozaan succession harbours a wealth of information on the crust-forming events that affected the Kaapvaal craton. Detrital zircons from quartzites and diamictite samples yield ages that record magmatic events that extend from the early (ca. 3.6Ga) to middle (2.89Ga) Archean. Late magmatic events were coeval with the development of the Mozaan basin. The Mozaan succession also is host to the oldest known glacial deposits, namely the Klipwal and the Mpatheni Member diamictites. The absence of deformation, erosional contacts and the presence of incorporated underlying material suggest that grounded glaciers were not the mode of deposition of these diamictites, but that the glacial deposits can be explained as gravity flows from collapse of oversteepened slopes of low relief glaciomarine setting that degenerated in more distal part of the basin into clast poor turbidity flows. Analysis of shale and matrix composition in diamictites show that mechanical erosion processes dominated the source area. CIA values range between 70 and 81, suggesting negligible chemical weathering in the sediment source area. CIA values increase only in the upper part of the stratigraphy, i.e. Ntanyana Formation. Incompatible to compatible trace element ratios are low and suggest that mafic and ultramafic rock dominated the source area. This, perhaps, demonstrates that the greenstone belts were a major source of detritus to the Mozaan basin. Well-constrained paleomagnetic data sets acquired from the Klipwal Member diamictite and Tobolsk lava give a very good estimate of the paleogeographic setting of the Kaapvaal craton during the deposition of the Mozaan Group. The Klipwal diamictite was apparently deposited at high-paleolatitude setting of 48°. The craton then moved slightly to the north to latitude ~43° at the time of eruption of the Tobolsk lavas. From the results it appears that available geochemical classification schemes based on the composition of Phanerozoic volcanic rocks are not suitable to classify the lavas of the Agatha Formation unequivocally. To arrive at any tectonic model for these igneous rocks it is necessary to consider stratigraphic relationships, physical volcanology and geochemical characteristics of the rock succession. On the other hand, the wellconstrained paleomagnetic data indicate that the global climate system in the Mesoarchean was similar to modern day earth where glacial deposits are constrained largely to Polar Regions.
- Full Text:
- Authors: Nhleko, Noah
- Date: 2009-01-28T09:42:41Z
- Subjects: Geology , Stratigraphic geology , Geochemistry , Paleomagnetism
- Type: Thesis
- Identifier: uj:14843 , http://hdl.handle.net/10210/1966
- Description: D.Phil. , The Mesoarchean Pongola Supergroup, cropping out in the southeastern region of the Kaapvaal craton, is one of the oldest known supracrustal successions in the world. It represents an erosional remnant of a once extensive cratonic cover sequence. The succession is subdivided into the lower Nsuze Group, a volcano sedimentary succession, and the Mozaan Group composed mainly of siliciclastics and minor volcanics. The Mozaan Group is host to the world’s oldest known glacial deposit. The Pongola Supergroup is well preserved both geochemically and structurally. Outcrops extend from the northern part of KwaZulu-Natal and Mpumalanga Province in South Africa into Swaziland. This study presents results of an integrated stratigraphic, sedimentological, geochemical, geochronological, and paleomagnetic investigation of the Pongola Supergroup in Swaziland and drill cores from the Nongoma Graben in KwaZulu-Natal. The Nsuze Group displays marked cyclicity between volcanic and siliciclastic rocks that were probably deposited in an intracratonic ‘sag and dome’ basin. The volcanicsedimentary cycles are thought to represent periodic heat loss from a hot regional mantle beneath the Kaapvaal craton. In the sag basins the rate of subsidence was gradual and sedimentation marked by near shore deposition. Volcanism in the Agatha Formation was episodic and displays a cyclicity of 2-14Myr in duration. Magmatic eruption was marked by the development of a low crustal level magma chamber. Crustal contamination trough assimilation and fractional crystallization at these low crustal level magma storages is recorded by compositional bimodal volcanism of basaltic andesite-rhyodacite and andesite-rhyolite association. After cessation of the volcanism of the Nsuze Group, subsequent development of the Pongola basin was marked by thermal subsidence and marine transgression in an epicratonic basin, at the time of deposition of the Mozaan Group. The Mozaan Group overlies the Nsuze Group with an erosive unconformity developed over an in situ weathering profile, i.e. a paleosol. The Mozaan Group consists of alternating quartzite, shale, conglomerate, iron-formation. Three units of contemporaneous flood basalt, namely the Tobolsk, Gabela and Ntanyana formations are interbedded with the siliciclastic deposits in the upper part of the succession. Unimodal paleocurrent directions based on fluvial quartzites indicate initial provenances to the south and north. This indicates that the basin morphology was in a form of a trough. Eventually paleocurrent distribution patterns turn southeast, and marine flooding extended further towards the west, to form the Greater Witwatersrand Basin, which was then modified by development of a foreland basin towards the west and northwest. This suggests that the present outcrops of the Mozaan Group represent mere remnants of an extensive basin. Siliciclastic deposits of the Mozaan succession harbours a wealth of information on the crust-forming events that affected the Kaapvaal craton. Detrital zircons from quartzites and diamictite samples yield ages that record magmatic events that extend from the early (ca. 3.6Ga) to middle (2.89Ga) Archean. Late magmatic events were coeval with the development of the Mozaan basin. The Mozaan succession also is host to the oldest known glacial deposits, namely the Klipwal and the Mpatheni Member diamictites. The absence of deformation, erosional contacts and the presence of incorporated underlying material suggest that grounded glaciers were not the mode of deposition of these diamictites, but that the glacial deposits can be explained as gravity flows from collapse of oversteepened slopes of low relief glaciomarine setting that degenerated in more distal part of the basin into clast poor turbidity flows. Analysis of shale and matrix composition in diamictites show that mechanical erosion processes dominated the source area. CIA values range between 70 and 81, suggesting negligible chemical weathering in the sediment source area. CIA values increase only in the upper part of the stratigraphy, i.e. Ntanyana Formation. Incompatible to compatible trace element ratios are low and suggest that mafic and ultramafic rock dominated the source area. This, perhaps, demonstrates that the greenstone belts were a major source of detritus to the Mozaan basin. Well-constrained paleomagnetic data sets acquired from the Klipwal Member diamictite and Tobolsk lava give a very good estimate of the paleogeographic setting of the Kaapvaal craton during the deposition of the Mozaan Group. The Klipwal diamictite was apparently deposited at high-paleolatitude setting of 48°. The craton then moved slightly to the north to latitude ~43° at the time of eruption of the Tobolsk lavas. From the results it appears that available geochemical classification schemes based on the composition of Phanerozoic volcanic rocks are not suitable to classify the lavas of the Agatha Formation unequivocally. To arrive at any tectonic model for these igneous rocks it is necessary to consider stratigraphic relationships, physical volcanology and geochemical characteristics of the rock succession. On the other hand, the wellconstrained paleomagnetic data indicate that the global climate system in the Mesoarchean was similar to modern day earth where glacial deposits are constrained largely to Polar Regions.
- Full Text:
Geochemistry and mineralogy of supergene altered manganese ore below the Kalahari unconformity in the Kalahari manganese field, Northern Cape Province, South Africa
- Authors: Du Plooy, Andries Petrus
- Date: 2009-01-28T09:38:57Z
- Subjects: Geology , Geochemistry , Mineralogy , Petrology , Manganese ores , Northern Cape (South Africa)
- Type: Thesis
- Identifier: uj:14834 , http://hdl.handle.net/10210/1958
- Description: M.Sc. , It is the focus of the study to qualitatively describe and then quantify the mineralogical and geochemical changes associated with the supergene alteration of carbonate-rich braunite lutite (Mamatwan-type ore) immediately below the Kalahari unconformity along the southeastern suboutcrop perimeter of the Hotazel Formation in the Kalahari deposit. It was also the objective of this study to determine the timing and duration of supergene alteration. Samples for polished thin sections were carefully selected from eight representative boreholes to be representative of all the lithostratigraphic zones and ore types. The thin sections were used to study mineralogy by means of reflected light microscopy and scanning electron microscopy. X-ray powder diffractometry on representative powder samples were used to study the mineralogy and geochemistry of the samples. Microprobe analyses were also performed on the representative samples. Finally the samples were submitted for 40Ar/39Ar geochronology. In this supergene enrichment zone carbonates are leached (associated with an increase in porosity) and Mn2+/Mn3+ -bearing minerals (kutnahorite, Mn-calcite an braunite) are altered to supergene Mn4+-bearing mineral phases (todorokite and manganomelane) and minor quartz. This process upgrades ore from 38 wt% Mn to ore with more than 40 wt% Mn. Element fluxes, enrichment and depletion of major and trace elements were quantified by mass balance calculations. Na2O, K2O, Sr, Ba, Zn and H2O were enriched, while Mn3O4, Fe2O3, CaO, MgO, P, B and CO2 were leached from the ore during supergene alteration. Results of this study suggest that the development of Post African I erosional surface may have taken place 45 Ma ago. The bottom of the weathering profile gives a well-defined peak at ca. 5 Ma that may possible coincide with the development of Post African II erosional surface. The major characteristics of the alteration process of the unaltered Mamatwan-type ore to supergene altered braunite lutite can be summarized as follow: • Leaching of Mn carbonates and Mn2+/Mn3+-oxides. • Formation of Mn4+-oxyhydroxides and quartz. • Decrease in relative density of the ore. • Increase in porosity of the ore. • Leaching of Mn3O4, Fe2O3, CaO, MgO, P, B, CO2. • Enrichment of Na2O, K2O, Sr, Ba, Zn, H2O. Chemical weathering processes along the Cenozoic Kalahari unconformity appear to have affected the manganiferous lithologies of the Hotazel Formation from 45 Ma onwards to 5 Ma. The weathering front processes very slowly through the Mn-rich braunite lutite (<10m in 40 Ma; <0.25m/Ma); producing a very uniform and microcrystalline supergene mineral assemblage with distinct characteristics.
- Full Text:
- Authors: Du Plooy, Andries Petrus
- Date: 2009-01-28T09:38:57Z
- Subjects: Geology , Geochemistry , Mineralogy , Petrology , Manganese ores , Northern Cape (South Africa)
- Type: Thesis
- Identifier: uj:14834 , http://hdl.handle.net/10210/1958
- Description: M.Sc. , It is the focus of the study to qualitatively describe and then quantify the mineralogical and geochemical changes associated with the supergene alteration of carbonate-rich braunite lutite (Mamatwan-type ore) immediately below the Kalahari unconformity along the southeastern suboutcrop perimeter of the Hotazel Formation in the Kalahari deposit. It was also the objective of this study to determine the timing and duration of supergene alteration. Samples for polished thin sections were carefully selected from eight representative boreholes to be representative of all the lithostratigraphic zones and ore types. The thin sections were used to study mineralogy by means of reflected light microscopy and scanning electron microscopy. X-ray powder diffractometry on representative powder samples were used to study the mineralogy and geochemistry of the samples. Microprobe analyses were also performed on the representative samples. Finally the samples were submitted for 40Ar/39Ar geochronology. In this supergene enrichment zone carbonates are leached (associated with an increase in porosity) and Mn2+/Mn3+ -bearing minerals (kutnahorite, Mn-calcite an braunite) are altered to supergene Mn4+-bearing mineral phases (todorokite and manganomelane) and minor quartz. This process upgrades ore from 38 wt% Mn to ore with more than 40 wt% Mn. Element fluxes, enrichment and depletion of major and trace elements were quantified by mass balance calculations. Na2O, K2O, Sr, Ba, Zn and H2O were enriched, while Mn3O4, Fe2O3, CaO, MgO, P, B and CO2 were leached from the ore during supergene alteration. Results of this study suggest that the development of Post African I erosional surface may have taken place 45 Ma ago. The bottom of the weathering profile gives a well-defined peak at ca. 5 Ma that may possible coincide with the development of Post African II erosional surface. The major characteristics of the alteration process of the unaltered Mamatwan-type ore to supergene altered braunite lutite can be summarized as follow: • Leaching of Mn carbonates and Mn2+/Mn3+-oxides. • Formation of Mn4+-oxyhydroxides and quartz. • Decrease in relative density of the ore. • Increase in porosity of the ore. • Leaching of Mn3O4, Fe2O3, CaO, MgO, P, B, CO2. • Enrichment of Na2O, K2O, Sr, Ba, Zn, H2O. Chemical weathering processes along the Cenozoic Kalahari unconformity appear to have affected the manganiferous lithologies of the Hotazel Formation from 45 Ma onwards to 5 Ma. The weathering front processes very slowly through the Mn-rich braunite lutite (<10m in 40 Ma; <0.25m/Ma); producing a very uniform and microcrystalline supergene mineral assemblage with distinct characteristics.
- Full Text:
Metasedimentary manganese ores of the Serra do Navio deposit, Amapa Province, Brazil
- Authors: Chisonga, Benny Chanda
- Date: 2009-01-27T07:18:17Z
- Subjects: Geology , Manganese ores , Petrology , Mineralogy , Fluid inclusions , Geochemistry , Amapá (Territory) Brazil
- Type: Thesis
- Identifier: uj:14828 , http://hdl.handle.net/10210/1952
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
- Authors: Chisonga, Benny Chanda
- Date: 2009-01-27T07:18:17Z
- Subjects: Geology , Manganese ores , Petrology , Mineralogy , Fluid inclusions , Geochemistry , Amapá (Territory) Brazil
- Type: Thesis
- Identifier: uj:14828 , http://hdl.handle.net/10210/1952
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
Geological and geochemical study of the quartzofeldspathic rocks from the farm Gotha, Limpopo Province, South Africa
- Authors: Barnett, Martina
- Date: 2009-01-27T07:17:45Z
- Subjects: Geology , Geochemistry , Petrology , Mineralogy , Structural geology , Limpopo (South Africa)
- Type: Thesis
- Identifier: uj:14824 , http://hdl.handle.net/10210/1949
- Description: M.Sc. , This study has served to expand the geological map of surroundings of the Venetia Mine (Limpopo Province, South Africa) incorporating the area lying south of the kimberlite deposit and bounded in the south by the Dowe-Tokwe fault. The most significant structural conclusion stemming from this mapping project is that the Venetia Synform seems to be tectonically separate from the surrounding area and actually forms a klippe (shallowly dipping thrust) against the Krone Metamorphic terrane and the Gotha Complex. Petrographic descriptions of quartzofeldspathic lithologies found in the Krone Metamorphic Terrane to the west of the Venetia klippe (Mellonig, 2004) are identical suggesting that they belong to the Gotha igneous complex. There are no differences in geochemical compositions of monzogranite to granodiorite, tonalite and quartz diorite from Farms Gotha and Venetia. The rocks are I-type granitoids that generally form in continental magmatic arcs. The amount of U and Th in the igneous rocks of the Farms Gotha and Venetia (contained in minerals found within quartz, plagioclase, amphibole and K-feldspar crystal boundaries and the magmatic zircons of the Farm Gotha samples) and the pattern produced by heat producing elements (Council for Geoscience Radiogenic Map), indicate that that the unexpectedly high concentration of these elements are not the result of regional metamorphism, but is the remnant of the final crystallisation phase of the magma of the area. REE plots of the Venetia Mine samples show negative Eu anomalies, indicating the presence of plagioclase and K-feldspar in the magma source of the Venetia mine samples. The assumption is, that most samples retained their original chemical compositions having experienced only weak deuteric alteration and no dynamic metamorphism.
- Full Text:
- Authors: Barnett, Martina
- Date: 2009-01-27T07:17:45Z
- Subjects: Geology , Geochemistry , Petrology , Mineralogy , Structural geology , Limpopo (South Africa)
- Type: Thesis
- Identifier: uj:14824 , http://hdl.handle.net/10210/1949
- Description: M.Sc. , This study has served to expand the geological map of surroundings of the Venetia Mine (Limpopo Province, South Africa) incorporating the area lying south of the kimberlite deposit and bounded in the south by the Dowe-Tokwe fault. The most significant structural conclusion stemming from this mapping project is that the Venetia Synform seems to be tectonically separate from the surrounding area and actually forms a klippe (shallowly dipping thrust) against the Krone Metamorphic terrane and the Gotha Complex. Petrographic descriptions of quartzofeldspathic lithologies found in the Krone Metamorphic Terrane to the west of the Venetia klippe (Mellonig, 2004) are identical suggesting that they belong to the Gotha igneous complex. There are no differences in geochemical compositions of monzogranite to granodiorite, tonalite and quartz diorite from Farms Gotha and Venetia. The rocks are I-type granitoids that generally form in continental magmatic arcs. The amount of U and Th in the igneous rocks of the Farms Gotha and Venetia (contained in minerals found within quartz, plagioclase, amphibole and K-feldspar crystal boundaries and the magmatic zircons of the Farm Gotha samples) and the pattern produced by heat producing elements (Council for Geoscience Radiogenic Map), indicate that that the unexpectedly high concentration of these elements are not the result of regional metamorphism, but is the remnant of the final crystallisation phase of the magma of the area. REE plots of the Venetia Mine samples show negative Eu anomalies, indicating the presence of plagioclase and K-feldspar in the magma source of the Venetia mine samples. The assumption is, that most samples retained their original chemical compositions having experienced only weak deuteric alteration and no dynamic metamorphism.
- Full Text:
Granitic and rhyolitic magmatism: constraints on continental reconstruction from geochemistry, geochronology and palaeomagnetism
- Authors: Carter, Lisa
- Date: 2009-01-27T07:17:25Z
- Subjects: Continental drift , Paleomagnetism , Geochemistry , Geological time , Rajasthan (India) , Seychelles , Madagascar
- Type: Thesis
- Identifier: uj:14822 , http://hdl.handle.net/10210/1947
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
- Authors: Carter, Lisa
- Date: 2009-01-27T07:17:25Z
- Subjects: Continental drift , Paleomagnetism , Geochemistry , Geological time , Rajasthan (India) , Seychelles , Madagascar
- Type: Thesis
- Identifier: uj:14822 , http://hdl.handle.net/10210/1947
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
A geological study of the Platreef at Potgietersrus platinum mine with emphasis on the magmatic processes, contamination and metasomatism
- Authors: Appiah-Nimoh, Frederick
- Date: 2009-01-27T07:17:16Z
- Subjects: Platinum group , Metasomatism (Mineralogy) , Magmatism , Geology , Geochemistry , Busveld complex (South Africa)
- Type: Thesis
- Identifier: uj:14821 , http://hdl.handle.net/10210/1946
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
- Authors: Appiah-Nimoh, Frederick
- Date: 2009-01-27T07:17:16Z
- Subjects: Platinum group , Metasomatism (Mineralogy) , Magmatism , Geology , Geochemistry , Busveld complex (South Africa)
- Type: Thesis
- Identifier: uj:14821 , http://hdl.handle.net/10210/1946
- Description: M.Sc. , Please refer to full text to view abstract
- Full Text:
Basin analysis of the Mesoproterozoic Bushmanland group of the Namaqua Metamorphic Province, South Africa
- Authors: McClung, Craig Randall
- Date: 2008-06-12T05:35:38Z
- Subjects: Geology , Geochemistry , Namaqualand (South Africa)
- Type: Thesis
- Identifier: uj:2666 , http://hdl.handle.net/10210/610
- Description: The Mesoproterozoic Bushmanland Subprovince of northwestern South Africa forms the western continuation of the transcontinental Namaqua-Natal Metamorphic Province, a crustal domain affected by the 1020-1220 Ma Namaquan Orogeny. Cross-cut by several large faults, the Bushmanland Subprovince can be subdivided into a southern Garies Terrain and northern Aggeneys Terrain. The supracrustal rocks of the Aggeneys Terrain (i.e. Bushmanland Group), comprise a thin (<1 km thick) metavolcano-sedimentary succession composed of a very consistent, shallow marine duplex of sandstone-shale to chemogenic metasedimentary and metavolcanic rocks that have undergone multiple phases of deformation and metamorphism. Since the discovery of the Broken Hill-type (BHT) mineralization in the Aggeneys-Gamsberg district (~440 Mt, 5.2% Cu+Zn+Pb) in the early 1970’s, controversy has persisted regarding the stratigraphy of the Bushmanland Group, its lateral correlation throughout the Aggeneys Terrain, environment and age of deposition, as well as classification and origin of its base-metal sulfide ± barite deposits. For these reasons, the present study primarily focuses on two aims, namely: (1) regionally based comprehensive lithostratigraphic, geochemical and geochronologic analysis of the Bushmanland Group to be used in the construction of a basin model; and (2) petrographic and geochemical analyses of Fe-Mn-rich rocks and barites to determine if they are related to base-metal mineralization and if so, to what extent. New lithostratigraphic data for the Bushmanland Group indicate that it can be subdivided into two subgroups and thirteen formations that are directly correlatable throughout the terrain as well as similar supracrustal successions in neighboring portions of the Namaqua Metamorphic Province. The base of the Bushmanland Group (Wortel Subgroup) comprises a thin (250-350 m thick) sequence of interbedded upward-coarsening psammo-pelitic schists and mature quartzite (i.e. meta-orthoquartzites) of the Namies Schist Fm., Pella Quartzite Fm., Bloemhoek Fm. and laterally equivalent Kangnas Fm. In contrast, the metasedimentary rocks of the unconformably overlying Kouboom Subgroup can be separated into facies terrains divided by the Pofadder-Tantalite Valley Shear Zone (PTV Shear Zone). West of the PTV Shear Zone the Kouboom Subgroup is characterized by a thin (205-225 m thick) succession of interbedded mature quartzites and pelitic schists. East of PTV Shear Zone the Kouboom Subgroup encompasses a thick (~1250 m thick) succession of calc-silicate rocks hosted by biotite to calc-silicate-rich schists and metagreywackes. The Koeris Fm., a variably thick (0-650 m) succession of psammitic schists, metaconglomerates and ortho-amphibolites unconformably overlies the Kouboom Subgroup. Geochemical provenance and detrital zircon core populations of the Wortel Subgroup suggest the metasedimentary rocks were derived from the Paleoproterozoic continental island arc rocks of the Vioolsdrift Intrusive Suite and Gladkop Suite, as well as an unidentified sedimentary/metasedimentary succession. Deposition took place in a passive continental margin environment between 1140 to 1650 Ma. In contrast, the unconformably overlying Kouboom Subgroup is characterized by larger plutonic derived zircons of the basement rocks to the Orange River Group, suggesting deposition in a tectonically active environment marked by repeated periods of tectonic uplift. In addition, new age constraints reveal that deposition in the upper part of the Kouboom Subgroup (possibly upper part of the Gams Fm.) was synchronous with emplacement of the Little Namaqualand Suite (~1190 Ma) into the lower portions, i.e. Wortel Subgroup, of the Bushmanland Group. The geochemical attributes and detrital zircon populations of metagreywackes from the Driekop Fm. suggest they were eroded from the newly exposed, i.e. fresh to poorly weathered, intrusions of the Little Namaqualand Suite, indicating a renewed period of tectonic uplift. Lastly, unlike the other lithologic units of the Bushmanland Group, the Koeris Fm. exhibits four detrital zircon age populations at 1125-1325, 1605-1695, 1730-1910 and 1935-2075 Ma. The older sub-populations indicate sediment derivation from various units of the Richtersveld Subprovince and Steinkopf Domain, while the younger sub-populations suggest derivation from various units in the Rehoboth Inlier of Namibia and the Gordonia Terrain to the east. The provenance signature of the younger subpopulation implies that deposition of the Koeris Fm. occurred after continental collision between the Rehoboth Inlier-Kaapvaal Craton and the Namaqua Metamorphic Province. With regards to the base-metal deposits of the Aggeneys-Gamsberg district, petrographic and geochemical analysis of the Bushmanland Group Fe-Mn-rich rocks suggests that they can be subdivided into several types: (1) primary Fe-Mn-rich metasedimentary rocks; (2) magnetite-amphibole-rich Fe-Mn-rich rocks; (3) coticules; and (4) epigenetic Fe-Mn-rich rocks. Primary Fe-Mn-rich metasedimentary rocks occur throughout the western and central portions of the study area and appear to have been formed through the deposition of Fe-Mn-rich hydrogenous precipitates in areas of localized sediment starvation. However, as illustrated by the primary Fe-Mn-rich metasedimentary rocks of the Lemoenpoort prospect, a syn-diagenetic, hot (>250°C), metalliferous hydrothermal fluids infiltrated and altered these hydrogenous Fe-Mnrich metasedimentary rocks, resulting in the deposition of base-metal sulfides, formation of magnetite-amphibolite-rich Fe-Mn-rich rocks, as well as hydrothermal alteration of the siliciclastic wall rocks to form coticules. The spatial restriction of epigenetic Fe-Mn-rich rocks to shear zones, high Fe2O3 T (ca. 65 wt %), low ΣREE (ca. 13 ppm), presence of recrystallized quartz crystals, elevated concentration of Cu in some occurrences and general similarities with some hydrothermal iron/iron-oxide copper-gold (IOCG) deposits, suggests that the epigenetic Fe-Mn-rich rocks may have formed during prograde metamorphism. Low concentrations of SrO (0.5 ± 0.2 wt %), highly radiogenic Sr/ Sr ratios (0.7164 ± 0.0028), elevated δ S (27.3 ± 4.9 ‰) and δ O (7.7 ± 3.1 ‰) values in the barites, as compared to contemporaneous Mesoproterozoic seawater, suggests precipitation of stratiform and stratabound barite layers in the Bushmanland Group occurred through mixing of an evolved continental crustal source and contemporaneous seawater sulfate, 87 86 34 18 modified by bacterial sulfate reduction. Most importantly, δ O values suggest possible minimum temperatures of formation ranging from 18 <150°C for the Gamsberg deposit to >250°C for occurrences in the Aggeneys area. These obvious differences in temperature of formation are in good agreement with the Cu-rich, Ba-poor nature of the sulfide mineralization characteristic of the Aggeneys deposits versus the Cu-poor, Ba-rich character of the Gamsberg deposit. In conjunction with this, the isotopic and petrographic arguments favor a sub-seafloor replacement model for the stratabound barite occurrences of the Aggeneys deposits, while at Gamsberg, deposition at the sediment-water interface as a true sedimentary exhalite appears more acceptable. Data obtained in the present study, combined with the results of previous investigations can be used to develop a comprehensive model for the geological evolution of the Aggeneys Terrain and Namaqua Metamorphic Province. The tectono-sedimentary evolution of the Aggeneys Terrain and Namaqua Metamorphic Province is marked by two important tectonic events separated by an episode of tectonic quiescence. Extrusion and deposition of the metavolcano-sedimentary rocks of the Orange River Group at 1908 Ma marks the start of the Orange River Orogeny. vii Prior to emplacement of the Vioolsdrift Intrusive Suite, the Orange River Group appears to have undergone a period of folding and low-grade metamorphism [D1/M1] that was subsequently followed by emplacement of the Main Phase Vioolsdrift Intrusive Suite roughly dated at 1890 Ma. Rapidly following emplacement of these intrusions, the lower crustal rocks of the Richtersveld Subprovince underwent a second, higher, amphibolite-facies metamorphic event [M1B] from 1870-1840 Ma. This event may have resulted in lower crustal melting and emplacement of the Gladkop Suite into an unknown package of metasediments or metasedimentary rocks south of the present day Orange River at roughly 1820 Ma. The Gladkop Suite was subsequently subjected to high-grade metamorphism at 1800 Ma. The Orange River Orogeny was terminated by emplacement of the Late Phase Vioolsdrift Intrusive Suite at approximately 1765 Ma and later northward-directed thrusting. Following termination of the Orange River Orogeny, deposition of the Bushmanland Group began in a tectonically stable environment marked by punctuated periods of tectonic activity that lasted until emplacement of the Little Namaqualand Suite at 1190 Ma. The detrital zircon populations of the Pella Quartzite Fm. and Koeris Fm. support (a) regional correlation of these stratigraphic units throughout the study area, (b) confirms sediment derivation from various local source terrains and (c) suggests a maximum depositional age of 1650 Ma. Furthermore, new age constraints reveal initiation of the O’okiepian Episode (Namaquan Orogeny), characterized by regional-scale mid- to high-grade contact metamorphism, was synchronous with emplacement of the Little Namaqualand Suite and deposition of the upper Kouboom Subgroup. Furthermore, the detrital zircon populations for the Driekop Fm. (upper Kouboom Subgroup) contain a large population of 1190 Ma (i.e. O’okiepian-age) detrital cores, suggesting a renewed period of tectonic uplift. Analogously, age constraints for the Koeris Fm. indicate a maximum depositional age of 1130 Ma, as well as derivation from a number of local and exotic source terrains indicating that deposition of the Koeris Fm. must have occurred in response to continental collision between the Rehoboth Inlier-Kaapvaal Craton and the Namaqua Metamorphic Province. Furthermore, these new age constraints also constrain the timing of D2-D3 deformation to between 1130-1080 Ma and regional peak metamorphism to 1020- 1040 Ma. , Prof. N.J. Beukes Prof. J. Gutzmer
- Full Text:
- Authors: McClung, Craig Randall
- Date: 2008-06-12T05:35:38Z
- Subjects: Geology , Geochemistry , Namaqualand (South Africa)
- Type: Thesis
- Identifier: uj:2666 , http://hdl.handle.net/10210/610
- Description: The Mesoproterozoic Bushmanland Subprovince of northwestern South Africa forms the western continuation of the transcontinental Namaqua-Natal Metamorphic Province, a crustal domain affected by the 1020-1220 Ma Namaquan Orogeny. Cross-cut by several large faults, the Bushmanland Subprovince can be subdivided into a southern Garies Terrain and northern Aggeneys Terrain. The supracrustal rocks of the Aggeneys Terrain (i.e. Bushmanland Group), comprise a thin (<1 km thick) metavolcano-sedimentary succession composed of a very consistent, shallow marine duplex of sandstone-shale to chemogenic metasedimentary and metavolcanic rocks that have undergone multiple phases of deformation and metamorphism. Since the discovery of the Broken Hill-type (BHT) mineralization in the Aggeneys-Gamsberg district (~440 Mt, 5.2% Cu+Zn+Pb) in the early 1970’s, controversy has persisted regarding the stratigraphy of the Bushmanland Group, its lateral correlation throughout the Aggeneys Terrain, environment and age of deposition, as well as classification and origin of its base-metal sulfide ± barite deposits. For these reasons, the present study primarily focuses on two aims, namely: (1) regionally based comprehensive lithostratigraphic, geochemical and geochronologic analysis of the Bushmanland Group to be used in the construction of a basin model; and (2) petrographic and geochemical analyses of Fe-Mn-rich rocks and barites to determine if they are related to base-metal mineralization and if so, to what extent. New lithostratigraphic data for the Bushmanland Group indicate that it can be subdivided into two subgroups and thirteen formations that are directly correlatable throughout the terrain as well as similar supracrustal successions in neighboring portions of the Namaqua Metamorphic Province. The base of the Bushmanland Group (Wortel Subgroup) comprises a thin (250-350 m thick) sequence of interbedded upward-coarsening psammo-pelitic schists and mature quartzite (i.e. meta-orthoquartzites) of the Namies Schist Fm., Pella Quartzite Fm., Bloemhoek Fm. and laterally equivalent Kangnas Fm. In contrast, the metasedimentary rocks of the unconformably overlying Kouboom Subgroup can be separated into facies terrains divided by the Pofadder-Tantalite Valley Shear Zone (PTV Shear Zone). West of the PTV Shear Zone the Kouboom Subgroup is characterized by a thin (205-225 m thick) succession of interbedded mature quartzites and pelitic schists. East of PTV Shear Zone the Kouboom Subgroup encompasses a thick (~1250 m thick) succession of calc-silicate rocks hosted by biotite to calc-silicate-rich schists and metagreywackes. The Koeris Fm., a variably thick (0-650 m) succession of psammitic schists, metaconglomerates and ortho-amphibolites unconformably overlies the Kouboom Subgroup. Geochemical provenance and detrital zircon core populations of the Wortel Subgroup suggest the metasedimentary rocks were derived from the Paleoproterozoic continental island arc rocks of the Vioolsdrift Intrusive Suite and Gladkop Suite, as well as an unidentified sedimentary/metasedimentary succession. Deposition took place in a passive continental margin environment between 1140 to 1650 Ma. In contrast, the unconformably overlying Kouboom Subgroup is characterized by larger plutonic derived zircons of the basement rocks to the Orange River Group, suggesting deposition in a tectonically active environment marked by repeated periods of tectonic uplift. In addition, new age constraints reveal that deposition in the upper part of the Kouboom Subgroup (possibly upper part of the Gams Fm.) was synchronous with emplacement of the Little Namaqualand Suite (~1190 Ma) into the lower portions, i.e. Wortel Subgroup, of the Bushmanland Group. The geochemical attributes and detrital zircon populations of metagreywackes from the Driekop Fm. suggest they were eroded from the newly exposed, i.e. fresh to poorly weathered, intrusions of the Little Namaqualand Suite, indicating a renewed period of tectonic uplift. Lastly, unlike the other lithologic units of the Bushmanland Group, the Koeris Fm. exhibits four detrital zircon age populations at 1125-1325, 1605-1695, 1730-1910 and 1935-2075 Ma. The older sub-populations indicate sediment derivation from various units of the Richtersveld Subprovince and Steinkopf Domain, while the younger sub-populations suggest derivation from various units in the Rehoboth Inlier of Namibia and the Gordonia Terrain to the east. The provenance signature of the younger subpopulation implies that deposition of the Koeris Fm. occurred after continental collision between the Rehoboth Inlier-Kaapvaal Craton and the Namaqua Metamorphic Province. With regards to the base-metal deposits of the Aggeneys-Gamsberg district, petrographic and geochemical analysis of the Bushmanland Group Fe-Mn-rich rocks suggests that they can be subdivided into several types: (1) primary Fe-Mn-rich metasedimentary rocks; (2) magnetite-amphibole-rich Fe-Mn-rich rocks; (3) coticules; and (4) epigenetic Fe-Mn-rich rocks. Primary Fe-Mn-rich metasedimentary rocks occur throughout the western and central portions of the study area and appear to have been formed through the deposition of Fe-Mn-rich hydrogenous precipitates in areas of localized sediment starvation. However, as illustrated by the primary Fe-Mn-rich metasedimentary rocks of the Lemoenpoort prospect, a syn-diagenetic, hot (>250°C), metalliferous hydrothermal fluids infiltrated and altered these hydrogenous Fe-Mnrich metasedimentary rocks, resulting in the deposition of base-metal sulfides, formation of magnetite-amphibolite-rich Fe-Mn-rich rocks, as well as hydrothermal alteration of the siliciclastic wall rocks to form coticules. The spatial restriction of epigenetic Fe-Mn-rich rocks to shear zones, high Fe2O3 T (ca. 65 wt %), low ΣREE (ca. 13 ppm), presence of recrystallized quartz crystals, elevated concentration of Cu in some occurrences and general similarities with some hydrothermal iron/iron-oxide copper-gold (IOCG) deposits, suggests that the epigenetic Fe-Mn-rich rocks may have formed during prograde metamorphism. Low concentrations of SrO (0.5 ± 0.2 wt %), highly radiogenic Sr/ Sr ratios (0.7164 ± 0.0028), elevated δ S (27.3 ± 4.9 ‰) and δ O (7.7 ± 3.1 ‰) values in the barites, as compared to contemporaneous Mesoproterozoic seawater, suggests precipitation of stratiform and stratabound barite layers in the Bushmanland Group occurred through mixing of an evolved continental crustal source and contemporaneous seawater sulfate, 87 86 34 18 modified by bacterial sulfate reduction. Most importantly, δ O values suggest possible minimum temperatures of formation ranging from 18 <150°C for the Gamsberg deposit to >250°C for occurrences in the Aggeneys area. These obvious differences in temperature of formation are in good agreement with the Cu-rich, Ba-poor nature of the sulfide mineralization characteristic of the Aggeneys deposits versus the Cu-poor, Ba-rich character of the Gamsberg deposit. In conjunction with this, the isotopic and petrographic arguments favor a sub-seafloor replacement model for the stratabound barite occurrences of the Aggeneys deposits, while at Gamsberg, deposition at the sediment-water interface as a true sedimentary exhalite appears more acceptable. Data obtained in the present study, combined with the results of previous investigations can be used to develop a comprehensive model for the geological evolution of the Aggeneys Terrain and Namaqua Metamorphic Province. The tectono-sedimentary evolution of the Aggeneys Terrain and Namaqua Metamorphic Province is marked by two important tectonic events separated by an episode of tectonic quiescence. Extrusion and deposition of the metavolcano-sedimentary rocks of the Orange River Group at 1908 Ma marks the start of the Orange River Orogeny. vii Prior to emplacement of the Vioolsdrift Intrusive Suite, the Orange River Group appears to have undergone a period of folding and low-grade metamorphism [D1/M1] that was subsequently followed by emplacement of the Main Phase Vioolsdrift Intrusive Suite roughly dated at 1890 Ma. Rapidly following emplacement of these intrusions, the lower crustal rocks of the Richtersveld Subprovince underwent a second, higher, amphibolite-facies metamorphic event [M1B] from 1870-1840 Ma. This event may have resulted in lower crustal melting and emplacement of the Gladkop Suite into an unknown package of metasediments or metasedimentary rocks south of the present day Orange River at roughly 1820 Ma. The Gladkop Suite was subsequently subjected to high-grade metamorphism at 1800 Ma. The Orange River Orogeny was terminated by emplacement of the Late Phase Vioolsdrift Intrusive Suite at approximately 1765 Ma and later northward-directed thrusting. Following termination of the Orange River Orogeny, deposition of the Bushmanland Group began in a tectonically stable environment marked by punctuated periods of tectonic activity that lasted until emplacement of the Little Namaqualand Suite at 1190 Ma. The detrital zircon populations of the Pella Quartzite Fm. and Koeris Fm. support (a) regional correlation of these stratigraphic units throughout the study area, (b) confirms sediment derivation from various local source terrains and (c) suggests a maximum depositional age of 1650 Ma. Furthermore, new age constraints reveal initiation of the O’okiepian Episode (Namaquan Orogeny), characterized by regional-scale mid- to high-grade contact metamorphism, was synchronous with emplacement of the Little Namaqualand Suite and deposition of the upper Kouboom Subgroup. Furthermore, the detrital zircon populations for the Driekop Fm. (upper Kouboom Subgroup) contain a large population of 1190 Ma (i.e. O’okiepian-age) detrital cores, suggesting a renewed period of tectonic uplift. Analogously, age constraints for the Koeris Fm. indicate a maximum depositional age of 1130 Ma, as well as derivation from a number of local and exotic source terrains indicating that deposition of the Koeris Fm. must have occurred in response to continental collision between the Rehoboth Inlier-Kaapvaal Craton and the Namaqua Metamorphic Province. Furthermore, these new age constraints also constrain the timing of D2-D3 deformation to between 1130-1080 Ma and regional peak metamorphism to 1020- 1040 Ma. , Prof. N.J. Beukes Prof. J. Gutzmer
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