List of Titles

Selected magnetostratigraphic studies in the main Karoo Basin (South Africa): implications for mass extinction events and the supercontinent of Pangea

- De Kock, Michiel Olivier

Authors: De Kock, Michiel Olivier
Date: 2009-01-27T07:18:31Z
Subjects: Stratigraphic geology , Paleomagnetism , Paleoclimatology , Pangaea (Geology) , Karoo Basin (South Africa)
Type: Thesis
Identifier: uj:14829 , http://hdl.handle.net/10210/1953
Description: M.Sc. , The Late Carboniferous to early Jurassic Karoo Supergroup of South Africa witnessed two of the “big five” Phanerozoic mass extinction events, and the formation and subsequent break-up of the supercontinent Pangea. The closure of the Permian Period witnessed the greatest biotic crisis in the history of life. What is known about the Permian-Triassic boundary (hereafter referred to as the PTB) comes almost exclusively from marine successions in Europe and Asia. Although a major extinction event has been recognized in terrestrial successions, surprisingly little is known about its effects and timing. The exact placement of the PTB in the Karoo basin is not well constrained due to shortcomings of stratigraphic methods employed to date. This has made it extremely difficult to correlate the mass extinction events in the marine and non-marine environments; however, paleomagnetic studies could provide answers to both problems of absolute placement and correlation of the PTB in non-marine and marine successions. The PTB appears to lie within an interval of reversed polarity in many marine successions. A detailed magnetostratigraphic survey across the presumed PTB in the Karoo succession at localities in the north and south of the main Karoo Bain reveal two magnetic chrons, reversed followed by normal (with the boundary close to the reversal), which extends to slightly younger results from a previous study that identified an N/R pattern, thereby identifying a R/N/R pattern. The normal chron might correlate with the long basal Triassic normal polarity interval and the reversed polarity zones above and below it known from marine successions in the Alps, Russia, Pakistan and China. The PTB is thought to be situated coincident with the LAD of Dicynodon and the event bed of Ward et al. (2000), apparently above but not necessarily diachronous with a lithology change from predominantly green- to predominantly red mudstone. This placement falls within a normal polarity interval, but could conceivably have taken place at a time of reverse polarity due to delayed acquisition of magnetic remanence. The idea of an extraterrestrial impact as the cause of the end-Permian mass extinctions is strongly enhanced by a synchronous relationship between them. The configuration of the supercontinent Pangea during this time of earth history has been the matter of debate for the last three decades, with numerous alternative reconstructions to the classic Pangea A1 having been proposed for the time preceding the Jurassic. Paleomagnetic data from the Karoo allow for the definition of a new paleopole for West Gondwanaland, which prove a valuable tool for evaluating these various reconstructions. It is neither consistent with a Pangea B-type not C reconstruction for Pangea during this time interval, because of geological ambiguities. The most likely solution to the problem is that of a persistent non-dipole field contribution to the geomagnetic field during this time. Approximately 50 million years later Pangea was unambiguously in a classic Pangea A1 configuration, and life on earth suffered yet another set back. The end-Triassic mass extinction, which marks the sequence boundary between the Triassic and the Jurassic, has not received as much attention as the other four big Phanerozoic biotic disasters. In the Karoo a pronounced turnover in faunal assemblages from typical Triassic fauna to Jurassic Fauna (dinosaurs) is seen in the Elliot Formation. Magnetostratigraphic study of localities in the north and south of the Karoo Basin provided a magnetic zonation pattern for the Elliot Formation, a tool that has led to the constraining of the sequence boundary to the transition from the lower Elliot Formation to the middle Elliot and added to the hypothesis that the faunal turnover is globally synchronous. The determination of a paleolatitude for the Elliot Formation in combination with characteristically arid lithologies (eolian sandstones) provided the base for the evaluation of the paleoclimate that characterized Pangea during the Late Triassic to Early Jurassic. Key words: Karoo Basin, Magnetostratigraphy, Mass Extinction, Paleoclimate, Paleogeography, Paleomagnetism, Pangea, Permian-Triassic, Triassic-Jurassic
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Distribution and geochronology of unconformity-bound sequences in paleoproterozoic Elim-Olifantshoek red beds: implications for timing of formation of Sishen-type iron ore and heavy carbonate carbon isotope excursion

- Da Silva, Richard

Authors: Da Silva, Richard
Date: 2012-08-16
Subjects: Iron ores , Geochronometry , Paleontology, Proterozoic , Carbon isotopes , Geological time , Griqualand West (South Africa)
Type: Thesis
Identifier: uj:9517 , http://hdl.handle.net/10210/5946
Description: M.Sc. , Bracketing the depositional age of the Gamagara/Mapedi to Lucknow and Olifantshoek succession in Griqualand West is important because it not only represents one of the oldest known red bed successions in the world but also hosts some of the first well preserved lateritic soil profiles and carbonates with heavy 13C values traditionally correlated with the so-called Lomagundi carbonate carbon excursion. In addition the ancient supergene very large high-grade hematite iron ore deposits of the Sishen-Postmasburg area on the Maremane dome are associated with the erosional unconformity at the base of the Gamagara Formation (a lateral equivalent of the Mapedi Formation). However, the depositional age of especially the Gamagara/Mapedi to Lucknow succession is under dispute because it has been considered a) correlative to the lower part of the Waterberg Group in the Transvaal area, with the implication that it is younger than the Bushveld Complex with an age of ~2,054 Ga, and b) correlative to the Dwaalheuwel-Magaliesberg succession of the pre-Bushveld Pretoria Group of the Transvaal Supergroup in the Transvaal area. The upper age limit of the Gamagara/Mapedi to Lucknow succession is defined by 1,92 Ga felsic volcanics in the overlying Neylan-Hartley succession of the Olifantshoek Group. The Hartley Lava Formation is overlain by Volop quartzites. This study involves age determinations of detrital zircon populations extracted from the basal Doornfontein conglomerate member of the Gamagara/Mapedi succession, and quartzites of the Gamagara/Mapedi, Lucknow, Neylan, Hartley and Volop Formations at various localities in Griqualand West. Based on field work, three unconformity-bound sequences are defined, namely the Gamagara/Mapedi-Lucknow, Neylan-Hartley and Volop sequences. Most interestingly quartzites of the Gamagara/Mapedi-Lucknow sequence contain abundant zircons with ages similar to that of the Bushveld Complex at ~2,054-2,06 Ga in addition to zircons as young as ~1,98-2,01 Ga. An exception is results on one sample of the Doornfontein Member analyzed so far (it is from the Rooinekke iron ore mine south of Postmasburg) that contains only zircons that are older than the Bushveld Complex with a rather prominent youngest population bracketed between 2,2 Ga and 2,32 Ga. The youngest detrital zircon populations in the Neylan-Hartley sequence are either slightly older than the Hartley lava or contain zircons with similar age to Hartley felsic lavas at 1,92 Ga. This sequence thus appears to have developed immediately prior to and coeval with Hartley volcanism. The overlying Volop sequence contains abundant zircons as young as ~1,89 Ga. The results clearly illustrate that the Gamagara/Mapedi to Lucknow succession is certainly not a lateral correlative of the pre-Bushveld Dwaalheuwel-Magaliesberg succession of the Pretoria Group. Rather it should be considered time-equivalent lower parts of the Waterberg Group in the Transvaal area. This implies that the heavy carbonate carbon excursion known from the Lucknow Formation is at least 100 my. younger than the one known from the upper part of the Silverton Formation along the contact with the overlying Magaliesberg Quartzite. There are thus at least three heavy carbonate carbon excursions, known from Paleoproterozoic cover successions of the Kaapvaal Craton in southern Africa, namely one in the ~2.35 Ga Duitschland Formation, a second in the ~2,1 Ga Silverton Formation of the Pretoria Group of the Transvaal Supergroup and the third in the ~1,98-1,92 Ga Lucknow Formation. It is further known that carbonates with normal open marine 13C values of close to zero occur in stratigraphic intervals between each of the heavy carbonate carbon excursions.
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Genesis and alteration of the Kalahari and Postmasburg manganese deposits, Griqualand West, South Africa.

- Gutzmer, Jens

Authors: Gutzmer, Jens
Date: 2012-08-15
Subjects: Manganese ores - South Africa , Manganese - South Africa , Manganese ores - Geology
Type: Thesis
Identifier: uj:9365 , http://hdl.handle.net/10210/5803
Description: Ph.D. , The economically important sedimentary manganese deposits of the Paleoproterozoic Kalahari and Postmasburg manganese fields, are situated in close geographic vicinity to each other in the Griqualand West region of the Northern Cape Province, South Africa. This thesis describes aspects of mineralogy, petrography and geochemistry of the manganese ores with the purpose to establish genetic models for genesis and alteration of manganese ores of both manganese fields. The Kalahari manganese field, situated some 60 km northwest of Kuruman, is the largest known land-based manganese deposit. Manganese ores occur interbedded with iron-formations of the Hotazel Formation of the Voelwater Subgroup of the Late Archean-Paleoproterozoic Transvaal Supergroup. The sediments of the Voelwater Subgroup are preserved in five erosional relics, of which the Kalahari manganese deposit is by far the largest and the only one of economic importance. Two types of ore are mined, low-grade sedimentary Mamatwan-type ore and high-grade Wesselstype ore. Mamatwan-type ore is represented by microcrystalline laminated braunite-lutite composed of kutnahorite, Mn-calcite, braunite and hematite, modified by the occurrence of late diagenetic or metamorphic hausmannite, partridgeite, manganite and calcite. Mamatwan-type ore contains up to 38 mass % Mn and constitutes about 97 % of the ore reserves in the Kalahari manganese deposit. High-grade Wessels-type ore, with a manganese content of between 42 to 48 mass % Mn (on average), constitutes about 3 % of the ore reserves. It occurs only in the northwestern part of the main Kalahari deposit, and in small deposits at Hotazel and Langdon, in association with a system of north-south striking normal faults. The Wessels alteration event is thought to be related to the Kibaran orogenetic event (about 1.1 Ga). Fault zones are ferruginized and alongside faults sedimentary Mamatwan-type ore has been hydrothermally upgraded to Wessels-type ore. Metasomatic fronts are defined by changing mineral associations. These associations clearly illustrate that decreasing degrees of alteration relate to increasing distance from the fluid feeders. Areas of unaltered Mamatwan-type ore are preserved in the core of fault blocks. Wessels-type ore consists mostly of hausmannite, bixbyite, braunite II and manganite and subordinate gangue minerals such as clinochlore and andradite but the mineral assemblage associated with the Wessels alteration event is unusually diverse. More than 100 minerals have been identified, amongst them 8 new mineral species and an unusual, ferrimagnetic, Fe-rich variety of hausmannite. Mass balance calculations illustrate that the upgrading of the Wessels-type manganese ore is a consequence of leaching of CaO, MgO, CO 2, and Si02 from a low-grade Mamatwan-type precursor. This metasomatic process results in increasing secondary porosities, compaction of the orebody to two thirds of its original thickness and consequently residual enrichment of manganese in the ores. Three younger alteration events are observed in the Kalahari manganese deposit. These are only of minor economic importance. Wallrock alteration associated with the Mamatwan alteration event is characterized by reductive leaching of Fe and Mn around syntectonic veins and joints with pyritechalcopyrite- carbonate mineralization. The alteration is explained by infiltration of epithermal solutions that were introduced along veins or joints. The timing of the alteration event has tentatively been placed into the Pre-Karoo era. The Smartt alteration event is associated with intensive faulthosted brecciation and replacement of braunite and carbonates of the Mamatwan-type ore by todorokite and manganomelane, a process that causes considerable upgrading of the manganese ore next to a fault breccia at Mamatwan mine, and the formation of stratiform cross-fibre todorokite veins at Smartt mine. The Smartt alteration event postdates the Mamatwan alteration event and has tentatively been correlated with Pre-Kalahari groundwater circulation. Supergene alteration of the ores took place in Kalahari and Post-Kalahari times. It is characterized by the occurrence of cryptomelane, pyrolusite and other typically supergene manganese oxides along the suboutcrop of the Hotazel Formation beneath the Cenozoic Kalahari Formation. The Postmasburg manganese field is situated about 120 km to the south of the Kalahari manganese field on the Maremane dome. Two arcuate belts of deposits extend from Postmasburg in the south to Sishen in the north. Two major ore types are present. The ferruginous type of ore is composed mainly of braunite, partridgeite and bixbyite and occurs along the centre of the Gamagara Ridge, or Western belt. The siliceous type of ore consists of braunite, quartz and minor partridgeite and occurs in small deposits along the Klipfontein Hills (or Eastern belt) and the northern and southern extremities of the Gamagara Ridge. Geological and geochemical evidence suggest that the manganese ores represent weakly metamorphosed wad deposits that accumulated in karst depressions during a period of lateritic weathering and karstification in a supergene, terrestrial environment during the Late Paleoproterozoic. The dolomites of the Campbellrand Group of the Transvaal Supergroup are host and source for the wad accumulations. Contrasting geological settings are suggested for the accumulation of the siliceous and the ferruginous types of ore respectively. The former originated as small pods and lenses of wad in chert breccia that accumulated in a karst cave system capped by the hematitized Manganore iron-formation of the Transvaal Supergroup. The cave system finally collapsed and the hematitized iron-formation slumped into the sinkhole structures. The ferruginous type of ore accumulated as mixed wad-clay sediment trapped in surficial sinkhole depressions in the paleokarst surface. The orebodies are conformably overlain by the Doornfontein hematite pebble conglomerate or aluminous shales belonging to the Gamagara Formation of the Late Paleoproterozoic Olifantshoek Group. Well preserved karst laterite paleosol profiles, described from the basal section of the Gamagara Formation, provide a strong argument for the terrestrial, supergene origin of the manganese ores. The manganese ores in the Postmasburg manganese field were affected by diagenesis and lower greenschist facies metamorphism. Metamorphism resulted in recrystallization to braunite in the siliceous ores of the Eastern belt, and to massive or mosaic textured braunite and idioblastic partridgeite in the ferruginous environment of the Western belt. Secondary karstification and supergene weathering are evidence for renewed subaerial exposure of the manganese ore and their host rocks. The metamorphic mineral assemblage is replaced by abundant romanechite, lithiophorite and other supergene manganese oxides. Comparison between the Kalahari- and the Postmasburg manganese field shows that sedimentary manganese accumulation took place in entirely different depositional environments and owing to different mechanisms. Their close geographic relationship appears to be coincidental. Apparent similarities arise as a consequence of regional geological events that postdate the deposition of the manganese ores. These similarities include the lower greenschist facies metamorphic overprint, an event tentatively related to thrusting and crustal thickening during the Kheis orogenetic event, and syn- to Post-Kalahari supergene alteration. The correlation of structurally controlled hydrothermal alteration events in the Kalahari manganese field and the Postmasburg manganese field remains difficult due to the absence of the necessary geochronological constraints.
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- da Silva, Richard

Authors: da Silva, Richard
Date: 2012-08-17
Subjects: Iron ore
Type: Thesis
Identifier: uj:2659 , http://hdl.handle.net/10210/6103
Description: M.Sc. , Bracketing the depositional age of the Gamagara/Mapedi to Lucknow and Olifantshoek succession in Griqualand West is important because it not only represents one of the oldest known red bed successions in the world but also hosts some of the first well preserved lateritic soil profiles and carbonates with heavy 13C values traditionally correlated with the so-called Lomagundi carbonate carbon excursion. In addition the ancient supergene very large high-grade hematite iron ore deposits of the Sishen-Postmasburg area on the Maremane dome are associated with the erosional unconformity at the base of the Gamagara Formation (a lateral equivalent of the Mapedi Formation). However, the depositional age of especially the Gamagara/Mapedi to Lucknow succession is under dispute because it has been considered a) correlative to the lower part of the Waterberg Group in the Transvaal area, with the implication that it is younger than the Bushveld Complex with an age of ~2,054 Ga, and b) correlative to the Dwaalheuwel-Magaliesberg succession of the pre-Bushveld Pretoria Group of the Transvaal Supergroup in the Transvaal area. The upper age limit of the Gamagara/Mapedi to Lucknow succession is defined by 1,92 Ga felsic volcanics in the overlying Neylan-Hartley succession of the Olifantshoek Group. The Hartley Lava Formation is overlain by Volop quartzites. This study involves age determinations of detrital zircon populations extracted from the basal Doornfontein conglomerate member of the Gamagara/Mapedi succession, and quartzites of the Gamagara/Mapedi, Lucknow, Neylan, Hartley and Volop Formations at various localities in Griqualand West. Based on field work, three unconformity-bound sequences are defined, namely the Gamagara/Mapedi-Lucknow, Neylan-Hartley and Volop sequences. Most interestingly quartzites of the Gamagara/Mapedi-Lucknow sequence contain abundant zircons with ages similar to that of the Bushveld Complex at ~2,054-2,06 Ga in addition to zircons as young as ~1,98-2,01 Ga. An exception is results on one sample of the Doornfontein Member analyzed so far (it is from the Rooinekke iron ore mine south of Postmasburg) that contains only zircons that are older than the Bushveld Complex with a rather prominent youngest population bracketed between 2,2 Ga and 2,32 Ga. The youngest detrital zircon populations in the Neylan-Hartley sequence are either slightly older than the Hartley lava or contain zircons with similar age to Hartley felsic lavas at 1,92 Ga. This sequence thus appears to have developed immediately prior to and coeval with Hartley volcanism. The overlying Volop sequence contains abundant zircons as young as ~1,89 Ga. The results clearly illustrate that the Gamagara/Mapedi to Lucknow succession is certainly not a lateral correlative of the pre-Bushveld Dwaalheuwel-Magaliesberg succession of the Pretoria Group. Rather it should be considered time-equivalent lower parts of the Waterberg Group in the Transvaal area. This implies that the heavy carbonate carbon excursion known from the Lucknow Formation is at least 100 my. younger than the one known from the upper part of the Silverton Formation along the contact with the overlying Magaliesberg Quartzite. There are thus at least three heavy carbonate carbon excursions, known from Paleoproterozoic cover successions of the Kaapvaal Craton in southern Africa, namely one in the ~2.35 Ga Duitschland Formation, a second in the ~2,1 Ga Silverton Formation of the Pretoria Group of the Transvaal Supergroup and the third in the ~1,98-1,92 Ga Lucknow Formation. It is further known that carbonates with normal open marine 13C values of close to zero occur in stratigraphic intervals between each of the heavy carbonate carbon excursions. The only unit that may still be correlated with part of the Pretoria Group is the Doornfontein Member at the base of the Gamagara/Mapedi succession. The correlation of this unit with the base of the Dwaalheuwel Formation and the Hekpoort paleosol of the Pretoria Group thus remain possible but analyses of additional samples are needed to make sure that the conglomerate, and by implication the ancient supergene Sishen-type iron ore deposits, does not also postdate the Bushveld Complex.
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