Comparative effects of corrosion on electroless-nickel plated A6061 alloys in DOT3 brake fluid
- Authors: Ajibola, Olawale O. , Olubambi, Peter A.
- Date: 2018
- Subjects: Corrosive Wear , Aluminum Substrate , Hydraulic Brake Fluid
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/291239 , uj:31623 , Citation: Ajibola, O.O. & Olubambi, P.A. 2018. Comparative effects of corrosion on electroless-nickel plated A6061 alloys in DOT3 brake fluid. International Journal of Engineering & Technology, 7 (2) (2018) 927-934.
- Description: Abstract: Aluminium alloys used in automobile brake master cylinder pistons wear by corrosion due to contamination and chemical reaction of the contacting brake fluid. The study investigates the corrosion of electroless-nickel (EN) deposition enhanced cast aluminium alloy master cylinder piston surfaces immersed in hydraulic brake oil. Cast specimens were produced from the as-received wrought A6061 alloy scrap by sand casting. EN plated as-received and cast aluminium alloys specimens were immersed fully in brake oil for 1680 hours and corrosion rates were determined every 24 hours. Test samples were characterised using the hardness tester, atomic absorption spectrometer, metallurgical photo-microscope, x-ray diffractometer; and SEM with EDX attachment. Both surfaces corroded in the order of electroless-nickel plated cast aluminium alloy (ENCA) < electroless-nickel plated as-received aluminium alloy (ENAA) at 0.0235 and 0.0251 rates (mg/mm2/y) results which showed improvement in the corrosion resistance with significant influence of electroless-nickel coating in reducing corrosion rates of aluminium alloy in brake oil.
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Effect of heat treatment on wear behaviour of rolled carbon steel in DOT4 brake fluid
- Authors: Ajibola, Olawale O. , Akinribide, Ojo J. , Akinwamide, Samuel O. , Olubambi, Peter A.
- Date: 2019
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/403861 , uj:33859 , Citation: Olawale O Ajibola et al 2019 IOP Conf. Ser.: Mater. Sci. Eng. 628 012014
- Description: Abstract: The wear of heat-treated rolled carbon steels (HTRCSs) were performed under dry and wet sliding in DOT4 brake fluid is successfully investigated and reported in the study. The HTRCSs samples were obtained by heating to and soaking the as-rolled carbon steel (ARCS) at 950 oC prior to quenching or cooling in different media at different selected temperatures between (20 and 250 oC) and atmospheric conditions. The microstructures and wear track patterns of specimens were evaluated using SEM and high-resolution metallurgical microscope. The sliding wear behaviour and wear track patterns of the specimens impressed under 10N normal loads and reciprocating mode was used to assess the wear damages. The obtained wear properties were compared in air and DOT4 fluid environments using Anton Paar TRB tribometer. The results obtained showed that enhanced wear behaviours were obtained from the oil and water quenched samples as compared with the air and furnace cooled samples. The HTRCSs samples are more tolerable than as-rolled sample (ARCS) under dry sliding. However, beside the influences of the heat treatments, the lubricating effect of DOT4 is more pronounced in the results. The CoF ranges from 0.105 to 0.137 for wet sliding while higher CoF values (0.378-0.934) were obtained in the dry sliding.
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Effect of heat treatment on wear behaviour of rolled carbon steel in DOT4 brake fluid
- Authors: Ajibola, Olawale. O. , Akinribide, Ojo J. , Akinwamide, Samuel O. , Olubambi, Peter A.
- Date: 2019
- Language: English
- Type: Conference proceedings
- Identifier: http://hdl.handle.net/10210/405099 , uj:34002 , Citation: Ajibola, O.O. et al. 2019. Effect of heat treatment on wear behaviour of rolled carbon steel in DOT4 brake fluid.
- Description: Abstract: The wear of heat-treated rolled carbon steels (HTRCSs) were performed under dry and wet sliding in DOT4 brake fluid is successfully investigated and reported in the study. The HTRCSs samples were obtained by heating to and soaking the as-rolled carbon steel (ARCS) at 950 oC prior to quenching or cooling in different media at different selected temperatures between (20 and 250 oC) and atmospheric conditions. The microstructures and wear track patterns of specimens were evaluated using SEM and high-resolution metallurgical microscope. The sliding wear behaviour and wear track patterns of the specimens impressed under 10N normal loads and reciprocating mode was used to assess the wear damages. The obtained wear properties were compared in air and DOT4 fluid environments using Anton Paar TRB tribometer. The results obtained showed that enhanced wear behaviours were obtained from the oil and water quenched samples as compared with the air and furnace cooled samples. The HTRCSs samples are more tolerable than as-rolled sample (ARCS) under dry sliding. However, beside the influences of the heat treatments, the lubricating effect of DOT4 is more pronounced in the results. The CoF ranges from 0.105 to 0.137 for wet sliding while higher CoF values (0.378-0.934) were obtained in the dry sliding.
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Electrochemical corrosion behavior of copper in graphene-based thermal fluid with different surfactants
- Authors: Borode, Adeola O. , Ahmed, Noor A. , Olubambi, Peter A.
- Date: 2021
- Subjects: Graphene Nanofluid , Potentiodynamic , Polarization
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/480878 , uj:43547 , Citation: Borode, A.O., Ahmed, N.A., Olubambi, P.A. 2021. Electrochemical corrosion behavior of copper in graphene-based thermal fluid with different surfactants. DOI: https://doi.org/10.1016/j.heliyon.2021.e05949
- Description: Abstract: This study investigates the effect of different surfactant-dispersed graphene nanofluid on the electrochemical behavior of copper. This study was achieved by measuring the open circuit potential and potentiodynamic polarization of copper in the nanofluids at room temperature. The test media includes surfactant-free graphene nanofluid and graphene nanofluid dispersed using four different surfactants, which are sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, Gum Arabic, and Tween 80. The surface characterization and elemental composition of the copper sample before and after the corrosion tests were determined using a scanning electron microscope coupled with energy-dispersive X-ray spectroscopy. The phase formation after corrosion was also evaluated by measuring X-ray diffraction. The quantity of copper dissolved in the test media was evaluated using an inductively coupled plasma mass spectrometry (ICP-MS). The open-circuit potential measurements revealed that the current free corrosion potential of copper in the different surfactant-aided graphene nanofluids are different. The electrochemical corrosion potential, Tafel slopes, and corrosion rates revealed the better corrosion performance of copper in the nanofluid of different surfactants in the increasing order GA, SDS, Tween 80, and SDBS. Copper in GA-based graphene nanofluid was found to have the lowest corrosion rate while that of SDBS has the highest corrosion rate. However, the ICP-MS result revealed a discrepancy in the corrosion behavior and quantity of copper dissolved in the different test media. This could be attributed to the dissimilar dissolutionredeposition rate of copper in different media.
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Fabrication of forced air cool austempered ductile iron and exploring its corrosion behaviour in a simulated mine water
- Authors: Ige, Oladeji O. , Olawale, Oluyemi J. , Oluwasegun, Kunle M. , Aribo, Sunday , Obadele, Babatunde A. , Olubambi, Peter A.
- Date: 2017
- Subjects: Austempering process , Forced air cool quenching , Austempered ductile iron
- Language: English
- Type: Conference proceedings
- Identifier: http://hdl.handle.net/10210/217627 , uj:21663 , Citation: Ige, O.O. et al. 2017. Fabrication of forced air cool austempered ductile iron and exploring its corrosion behaviour in a simulated mine water. International Conference on Sustainable Materials Processing and Manufacturing, SMPM 2017, 23-25 January 2017, Kruger National Park
- Description: Abstract: The production of austempered ductile iron (ADI) with uniform microstructure and properties is constrained by the austempering process vis-à-vis the quenching medium. This is as a result of the stringent operating parameters with costly facilities. This limitation has restricted the application of ADI, despite its inherent mechanical and chemical properties. An emerging technology of overcoming this limitation is by austempering with force air cooling equipment, which is accessible, available and cost-efficient. This work characterizes the behaviour of the forced air cool ADI in simulated mine water due to the strategic importance of the mining industry in the global economy. The study establishes the influence of sample section thickness on the corrosion performance. The sample’s thickness were 5, 15, and 20 mm. Electrochemical experiments were performed on the forced air cool ADI at atmospheric pressure and room temperature with method such as open circuit potential (OCP). The post-corrosion analyses were performed using X-ray diffractometry (XRD) and field emission scanning electron microscopy (FESEM). The research highlighted that small section thickness has a more favourable performance compared with larger section. Consideration is also accorded to the capability of the ADI in the studied environment.
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Influence of single and double-atom metal doping on the electrocatalytic hydrogen evolution activity of 2D-MoS2 surface
- Authors: Mohlala, Lesego M. , Oviroh, Peter O. , Jen, Tien-Chien , Olubambi, Peter A.
- Date: 2020
- Subjects: Atomic doping , Density functional theory , Hydrogen evolution reaction
- Language: English
- Type: Conference Proceedings
- Identifier: http://hdl.handle.net/10210/461510 , uj:41110 , Citation: Mohlala, L.M. et al. 2020. Influence of single and double-atom metal doping on the electrocatalytic hydrogen evolution activity of 2D-MoS2 surface.
- Description: Abstract: The Hydrogen evolution reaction (HER) is an important process during electrocatalytic water splitting for hydrogen energy generation. Two dimensional (2D) MoS2 has been considered as a promising alternative to Pt-based catalysts in the hydrogen evolution reaction. However, the highest contribution for the catalytic activity of 2D-MoS2 is from its edge sites, this in turn leaves many in-plane domains useless. In this study, the effect of single atom metal (Pt, Ni and Pt-Ni) doping on HER catalytic activity of in-plane atoms was investigated using density functional theory calculations. The Gibbs free energy of adsorbed hydrogen on pristine MoS2 decreased from 1.86eV to -0.08eV in PtNi co-doped MoS2. This demonstrates enhanced catalytic activity of MoS2 due to atomic doping. The enhanced catalytic activity may also be attributed to the observed changes and increase in the density of electronic states near the Fermi energy level.
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Initial reaction mechanism on the atomic layer deposition of platinum on a graphene surface : a density functional theory study
- Authors: Mohlala, Lesego M. , Jen, Tien-Chien , Olubambi, Peter A.
- Date: 2019
- Subjects: ALD , DFT , Finite temperature
- Language: English
- Type: Conference proceedings
- Identifier: http://hdl.handle.net/10210/400059 , uj:33371 , Citation: Mohlala, L.M., Jen, T.C. & Olubambi, P.A. 2019. Initial reaction mechanism on the atomic layer deposition of platinum on a graphene surface : a density functional theory study.
- Description: Abstract: The atomic layer deposition (ALD) of platinum on carbon supports has been studied extensively due to the wide potential application in microelectronics and catalysis. The initial reaction mechanism of atomic layer deposited platinum on a hydroxylated graphene surface has been investigated using density functional theory (DFT). Methylcyclopentadienyl trimethylplatinum (MeCpPtMe3) and molecular oxygen were adopted as precursors. In addition, finite temperature calculations were performed to investigate the effect of process conditions. The free energies were calculated at temperatures 200°C and 300°C with pressure of 1Pa. The results obtained from the simulations were compared and correlated with available literature.
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Stability Assessment of Pipeline Cathodic Protection Potentials under the Influence of AC Interference
- Authors: Shabangu, Thabane H. , Shrivastava, Purva , Abe, Bolanle T. , Olubambi, Peter A.
- Date: 2018
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/279698 , uj:30041 , Citation: Shabangu, T.H., Shrivastava, P. & Abe, B.T. 2018. Stability Assessment of Pipeline Cathodic Protection Potentials under the Influence of AC Interference. Progress In Electromagnetics Research M, Vol. 66, 19–28. , Citation: Shabangu, T.H., Shrivastava, P. & Abe, B.T. 2018. Stability Assessment of Pipeline Cathodic Protection Potentials under the Influence of AC Interference.
- Description: Abstract: Metallic pipelines are protected from induced corrosion by the application of coating and Cathodic Protection (CP) systems. The latter is achieved by keeping the pipeline at a constant Direct Current (DC) voltage in relation to the surrounding soil. While this is conventionally meant to arrest corrosion, the Alternating Current (AC) interference from high voltage transmission lines has been a major problem to the CP potential systems of buried steel pipelines. Several research studies dealing with this problem have been published, and a lot of research work is still on going. This work focuses on assessing the stability of the CP potentials under the influence of AC interference. Seven different CP potentials varying from −800 mV to −1200 mV were applied on steel pipe specimen exposed to the AC interference with a varying AC voltage from 0–50 V. The results of the laboratory investigation revealed that CP potential of −1150 mV was more stable under the influence of AC interference, with just a minimal shift from the set value. The results from the corrosion morphology tests on the pipelines using Scanning Electron Microscope (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) reveal the need for optimising the CP potential to provide adequate or optimum protection to the pipelines. Thus, more research studies involving simulation and field studies may lead to a major breakthrough in improving protection potentials.
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Structural characterization and mechanical properties of pearlite – Enhanced micro-alloyed ductile irons
- Authors: Omole, Sylvester O. , Akinlabi, Oyetunji , Alaneme, Kenneth K. , Olubambi, Peter A.
- Date: 2020
- Subjects: Alloying , Pearlite , Ferrite
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/451631 , uj:39804 , DOI: https://doi.org/10.1016/j.jksues.2018.11.008 , Citation: Omole, S.O. et al. 2020. Structural characterization and mechanical properties of pearlite – Enhanced micro-alloyed ductile irons.
- Description: Abstract: The structural characteristic and mechanical properties of ductile irons micro alloyed with lean additions of molybdenum, nickel, copper and chromium was investigated. This was aimed at assessing the potentials of the utilization of lean ferro alloy additions (which offers reduced processing and product costs) for enhancing pearlite phase proportion, which is required for improved mechanical performance of ductile irons. The ductile irons contained a maximum of 0.2% each of Mo, Ni, Cu, and Cr and were processed using a crucible furnace. They were characterized using optical microscopy and X-ray diffractometry while hardness and tensile testings were used to evaluate the mechanical properties. The results show that the micro alloyed samples contain new compound of alloying elements with iron and the base alloy phase (FeSi, a Fe). It was also observed that the micro alloy additions resulted in significant increase in pearlite proportion from 30.63% in the base alloy to as much as 59.38% in the composition containing Mo, Ni and Cu as micro addition. Increase in hardness within the range 1.4–36.5% was obtained, while tensile strength increase within the range 35.89–80.55% with the use of the micro alloying additions. Overall, the best combination of mechanical properties was achieved for the ductile irons composition containing chromium and copper, as well as the one containing molybdenum, nickel and chromium as micro alloy additions.
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Structural characterization and mechanical properties of pearlite – enhanced micro-alloyed ductile irons
- Authors: Omole, Sylvester O. , Oyetunji, Akinlabi , Alaneme, Kenneth K. , Olubambi, Peter A.
- Date: 2020
- Subjects: Alloying , Pearlite , Ferrite
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/464040 , uj:41435 , Citation: Omole, S.O. et al. 2020. Structural characterization and mechanical properties of pearlite – enhanced micro-alloyed ductile irons. , DOI: https://doi.org/10.1016/j.jksues.2018.11.008
- Description: Abstract: Please refer to full text to view abstract.
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The effects of particle size distribution and sintering conditions on bending strength of sintered Ni-30þ alloys
- Authors: Shongwe, Mxolisi B. , Ajibola, Olawale O. , Ramakokovhu, Munyadziwa M. , Olubambi, Peter A.
- Date: 2018
- Subjects: Sintering , Grains , Bending Strength
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/291248 , uj:31624 , Citation: Shongwe, M.B. et al. The effects of particle size distribution and sintering conditions on bending strength of sintered Ni-30þ alloys. International Journal of Engineering & Technology, 7 (3) (2018) 1581-1584.
- Description: Abstract: Please refer to full text to view abstract.
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Wear and corrosion of wrought a6061 aluminium alloy in dot3 brake fluid
- Authors: Ajibola, Olawale O. , Ige, Oladeji O. , Olubambi, Peter A.
- Date: 2018
- Subjects: Hydraulic Brake Fluid , Piston Application , Wear
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/263343 , uj:27838 , Citation: Ajibola, O.O., Ige, O.O. & Olubambi, P.A. 2018. Wear and corrosion of wrought a6061 aluminium alloy in dot3 brake fluid. International Journal of Engineering & Technology, 7 (2):512-519.
- Description: Abstract: The twofold impact of wear and corrosion on wrought A6061 alloy in hydraulic DOT3 brake fluid environment was studied. The wear studies were performed on the samples using a developed wear-jig. Weight loss corrosion test method was used to determine the corrosion rate of the wrought A6061 alloy samples immersed in the brake fluid for a total of 1680 hours. From the results of wear tests carried out on the A6061 alloy sample with brake oil, the highest wear value of 5.24x10-7 mg/mm2/cycle (approx.) was obtained from 6 N (approx) force after 130 minutes. The wrought A6061 alloy material demonstrated the highest corrosion rates nearly 3.0 x10-2 mg/mm2/yr within the early 168 hours of immersion in brake fluid. The result is practically lower than the corrosion rate of cast specimen in DOT3 brake oil or some other alloys immersed in other corrosive media that were previously reported in the literature. The results show that small amount of chemical corrosion is sufficient to cause and accelerate mechanical wear of the material in usage.
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Wear and Corrosion of Wrought A6061 Aluminium Alloy in DOT3 Brake Fluid
- Authors: Ajibola, Olawale O. , Ige, Oladeji O. , Olubambi, Peter A.
- Date: 2018
- Subjects: Hydraulic Brake Fluid , Piston Application , Wear
- Language: English
- Type: Article
- Identifier: http://hdl.handle.net/10210/279684 , uj:30040 , Citation: Ajibola, O.O., Ige, O.O. & Olubambi, P.A. 2018. Wear and Corrosion of Wrought A6061 Aluminium Alloy in DOT3 Brake Fluid. International Journal of Engineering & Technology, 7 (2) (2018):512-519.
- Description: Abstract: The twofold impact of wear and corrosion on wrought A6061 alloy in hydraulic DOT3 brake fluid environment was studied. The wear studies were performed on the samples using a developed wear-jig. Weight loss corrosion test method was used to determine the corrosion rate of the wrought A6061 alloy samples immersed in the brake fluid for a total of 1680 hours. From the results of wear tests carried out on the A6061 alloy sample with brake oil, the highest wear value of 5.24x10-7 mg/mm2/cycle (approx.) was obtained from 6 N (approx) force after 130 minutes. The wrought A6061 alloy material demonstrated the highest corrosion rates nearly 3.0 x10-2 mg/mm2/yr within the early 168 hours of immersion in brake fluid. The result is practically lower than the corrosion rate of cast specimen in DOT3 brake oil or some other alloys immersed in other corrosive media that were previously reported in the literature. The results show that small amount of chemical corrosion is sufficient to cause and accelerate mechanical wear of the material in usage.
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Wear behaviour of cast aluminium silicon (Al-Si) alloy in Dot 4 brake fluid
- Authors: Ajibola, Olawale O. , Aribo, Sunday , Ige, Oladeji O. , Akinribide, Ojo J. , Akinwamide, Samuel O. , Olubambi, Peter A.
- Date: 2019
- Language: English
- Type: Conference proceedings
- Identifier: http://hdl.handle.net/10210/403851 , uj:33858 , Citation: Olawale O Ajibola et al 2019 IOP Conf. Ser.: Mater. Sci. Eng. 628 012012
- Description: Abstract: The frictional sliding behaviour of cast Al-Si alloy was investigated with and without DOT 4 hydraulic brake fluid lubrication/environments. Cast Al-Si specimen was produced from wrought alloy and the specimen surface was metallurgically prepared. The ascast product was characterized with aid of micro-hardness tester, the chemical composition was analysed by X-ray fluorescence (XRF), while X-ray diffraction (XRD) was used to identify phases present, microstructures and surface examinations were done on a high resolution metallurgical Optical Microscope. The properties of the polished and worn sample surfaces were examined by Scanning electron microscope (SEM) equipped with Energy dispersive Xray (EDS) facilities. A 6mm diameter alumina ball under varying normal loads (3-10 N) was rubbed against the surface of the cast Al-Si coupon specimen. The dry and wet sliding wear behaviour was assessed based on the CoF-sliding time behaviour. From the results, the average CoF values of 0.9064 for dry and 0.2038 for wet contacts were obtained. Comparatively, 1.03E-06 and 4.21E-07 minimum wear intensities; and 467290 and 132170 wear resistances were obtained for dry and wet contacts respectively. Behaviour of cast Al-Si in DOT4 were compared with its performance in DOT3 regarding the hydraulic brake system application.
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