Abstract
The significant structural feature in the title Ag
I
complex is the small bite angle of the nitrito ligand [49.80 (5)°], which influences the overall geometry.
The molecular structure of the title Ag
I
complex, [Ag(NO
2
)(C
18
H
12
F
3
P)
2
], features a distorted tetrahedral geometry about the central Ag
I
atom, with a total range of bond angles spanning from 49.80 (5) to 114.92 (1)°. The distortion arises primarily due to the small bite angle [49.80 (5)°] of the nitrito ligand. The compound crystallizes with one molecule in the asymmetric unit, in the space group
P
2
1
/
n
, with
Z
= 4 and
Z
′ = 1.