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Isomeric Dichloropyrazine of Dual-Function Additives: Synergistic Enhancement of Lithium Anode Protection and Sulfur Redox Kinetics in Lithium-Sulfur Batteries
Journal article   Open access

Isomeric Dichloropyrazine of Dual-Function Additives: Synergistic Enhancement of Lithium Anode Protection and Sulfur Redox Kinetics in Lithium-Sulfur Batteries

Nie, Kunlun, Fu, Qianqian, Wang, Min, Teng, Chao, Gao, Ruili, Ma, Xianguo, Wang, Xuyun, Ren, Jianwei, Wang, Rongfang and Wang, Hui
2024
Handle:
https://hdl.handle.net/10210/506468

Abstract

Lithium-sulfur batteries (LSBs) currently face challenges such as low sulfur utilization, inadequate cycling stability, and unstable lithium anode interfaces. In this study, dichloropyrazines (DCPs) are introduced as dual-functional additives into electrolyte and 2,5-DCP exhibits the most promising performance enhancement. This superiority can be attributed to its strong redox activity, lower molecular orbital energy gap, and
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