Abstract
Understanding the magnetic ground states of double perovskites remains complex due to competing exchange interactions, spin-orbit coupling, and structural disorder. This study explores the substitution of Cu2 + for Co2 + in La2CoRuO6 (LCRO), integrating experimental and DFT methods to probe the structural and electronic effects influencing magnetism. Pristine LCRO exhibits a monoclinic P21/c phase with dominant antiferromagnetic (AFM) Co2 +-O-Ru4 + interactions. Low-level Cu2 + substitution (x = 0.05 and 0.3) induces a strain-driven transformation to a tetragonal I4/m phase, introducing structural inhomogeneity and mixed valence states. These lead to competing ferromagnetic (FM) interactions (Cu2 +-O-Ru4 +/Cu2 +), while AFM order partially persists at x = 0.3 due to orbital asymmetry and strain effects. Magnetic measurements and DFT calculations show a Neel temperature (T N) shift from 28.7 to 39.8 K (x = 0.05), and emerging FM behavior at 19.2 K. At x = 0.3, AFM suppression and a Curie temperature (T C) of 36.5 K reveal dominant FM pathways. Finite-size corrected Curie-Weiss analysis highlights the role of strain and particle size in modulating magnetic properties and restoring intrinsic behavior in larger particles.