Abstract
The Cu NDs/Fe2O3 Mott-Schottky heterojunction promoted the electron transfer from the Cu metal to Fe2O3 semiconductive. The built-in electric field from Cu to Fe2O3 may improve the adsorption of O2 and OH−, thereby enhancing the electrocatalytic activity for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER).
[Display omitted]
•The Cu NDs/Fe2O3-NPCs was developed by creating Cu NDs/Fe2O3 Mott-Schottky heterojunction.•The Mott-Schottky built-in electric field from Cu to Fe2O3 may improve the adsorption of O2/OH−.•The bifunctional oxygen electrocatalysis exhibits outstanding performance for ZABs.
The fast electron transfer is a prerequisite to develop the high-performance bifunctional electrocatalysts for rechargeable Zn-air batteries (ZABs). In this work, the Mott-Schottky electrocatalyst Cu NDs/Fe2O3-NPCs was developed by creating Cu nanodots (NDs)/Fe2O3 heterojunction nanoislands rooted on N-rich porous carbon nanosheets (NPCs). The formed Mott-Schottky heterojunction Cu NDs/Fe2O3 nanoislands promoted the electron transfer from the metallic Cu to the semiconductive Fe2O3 phase, as a result, the adsorptions towards O2 and OH− species were improved, and sequentially the catalytic activities for both oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) were both remarkably enhanced. In addition, the porous nature of the developed catalyst also contributed to the effectiveness of the required mass transfer. The optimal Mott-Schottky Cu NDs/Fe2O3-NPCs catalyst exhibited an onset potential of 0.98 V and a Tafel slop of 53.7 mV dec-1 for ORR, and an overpotential of 328 mV at 10 mA cm−2 for OER. Further, the ZAB assembled with Cu NDs/Fe2O3-NPCs catalyst displayed a high power density of 138 mW cm−2 and an excellent long-term cyclability.