Abstract
M.Tech. (Chemical Engineering)
Greenhouse gas emissions and municipal solid waste management have presented challenges globally. This study aims to help mitigate these challenges by producing renewable energy from landfill food waste. Food waste is carbon neutral since plants use carbon dioxide for growth, so its application in coal-fired boilers will reduce the amount of carbon dioxide emissions thereby mitigating greenhouse effects. The problem with food waste is that it has high moisture content and it is heterogeneous. This limits its heating value and increases energy requirements for grinding. This study investigated the possibility of upgrading the fuel properties of food waste to produce biochar with similar properties to bituminous coal. The food waste was treated by torrefaction. The main aim was to optimize torrefaction conditions and analyze thermal evolution of the sample during torrefaction.
The food waste samples were collected from Marie Louis landfill site in Soweto. The samples were dried and milled for particle size reduction. The samples were further analyzed by proximate and ultimate analyses to determine its fuel properties and elemental composition before torrefaction. A tube furnace was used for the torrefaction process. Temperature was varied from 200 – 300 oC at a constant residence time of 40 min and 10 oC/min heating rate. Calorific value, mass yield, energy yield and energy density were computed and used to determine the appropriate torrefaction temperature. Residence time was then varied from 20 – 60 min at a constant torrefaction temperature of 275 oC and 10 oC/min heating rate. Heating rate was then varied keeping residence time at 20min and torrefaction temperature at 275 oC. Torrefaction temperature had a more pronounced effect than residence time and heating rate. The calorific value was upgraded from 19.76 MJ/kg for dried raw food waste to 26.15 MJ/kg for torrefied food waste at the optimum conditions which were 275 oC, 20 min and 10 oC/min. The higher heating value was comparable to that of bituminous coal currently being used for power generation in South Africa. Elemental analysis of biochar showed an increase in carbon content with temperature due to loss of oxygen containing volatiles. It was also observed that biochar obtained at the optimum conditions could easily be pelletized since it assumed the shape of the crucible...