Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron.

Ntaoleng Maureen Makunya

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Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron.

Dissertation

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Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron.

Ntaoleng Maureen Makunya

Undetermined, University of Johannesburg

15/05/2008

Handle:

https://hdl.handle.net/10210/393

Abstract

ligands

iron compounds synthesis

organometallic chemistry

The aim of this study was to investigate the mechanism of phosphine induced migratory carbonyl insertion in the monocyclopentadienyliron(II) carbonyl complex, [η5- (C5H5)Fe(CO)2Me], upon variation of different parameters such as the type and the concentration of the phosphine ligand and the solvent. The mechanism that agrees with the results obtained is presented below. Prof. A. Roodt

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Title: Tertiary phosphine induced migratory carbonyl insertion in cyclopentadienyl complexes of iron.
Creators - without role: Ntaoleng Maureen Makunya
Awarding Institution: University of Johannesburg; Undetermined
Theses and Dissertations: Undetermined, University of Johannesburg
Identifiers: 9910549407691
Academic Unit: University of Johannesburg; Department of Chemical Sciences
Resource Type: Dissertation